Polyaminoborane main chain scission using N-heterocyclic carbenes; formation of donor-stabilised monomeric aminoboranes

Naomi E. Stubbs; Titel Jurca; Erin M. Leitao; Christopher H. Woodall; Ian Manners

doi:10.1039/c3cc44373f

Polyaminoborane main chain scission using N-heterocyclic carbenes; formation of donor-stabilised monomeric aminoboranes

Naomi E. Stubbs
, Titel Jurca
, Erin M. Leitao
, Christopher H. Woodall
, Ian Manners^*

^*Corresponding author for this work

Research output: Contribution to journal › Article (Academic Journal) › peer-review

48 Citations (Scopus)

Abstract

The reaction of N-heterocyclic carbenes with polyaminoboranes [MeNH-BH2](n) or [NH2-BH2](n) at 20 degrees C led to depolymerisation and the formation of labile, monomeric aminoborane-NHC adducts, RNH-BH2-NHC (R = Me or H); a similar NHC adduct of Ph2N=BCl2 was characterized by single crystal X-ray diffraction.

Original language	English
Pages (from-to)	9098-9100
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	80
DOIs	https://doi.org/10.1039/c3cc44373f
Publication status	Published - 2013

Keywords

MOLECULAR-WEIGHT POLYAMINOBORANES
AMINE-BORANE ADDUCTS
AMMONIA-BORANE
HYDROGEN-TRANSFER
PHOSPHINE-BORANE
DEHYDROGENATION
CHEMISTRY
MECHANISM
PRECURSOR
STORAGE

Access to Document

10.1039/c3cc44373f

Handle.net

Persistent link

Catalytic Dehydrocoupling of Amine-Borane Adducts: A Route to Polyaminoboranes, Boron-Nitrogen Analogues of Polyolefins
Manners, I. (Principal Investigator)
1/08/10 → 1/02/14
Project: Research

Cite this

@article{d1d30e4fb7b74c5e828600dfc9d70f98,

title = "Polyaminoborane main chain scission using N-heterocyclic carbenes; formation of donor-stabilised monomeric aminoboranes",

abstract = "The reaction of N-heterocyclic carbenes with polyaminoboranes [MeNH-BH2](n) or [NH2-BH2](n) at 20 degrees C led to depolymerisation and the formation of labile, monomeric aminoborane-NHC adducts, RNH-BH2-NHC (R = Me or H); a similar NHC adduct of Ph2N=BCl2 was characterized by single crystal X-ray diffraction.",

keywords = "MOLECULAR-WEIGHT POLYAMINOBORANES, AMINE-BORANE ADDUCTS, AMMONIA-BORANE, HYDROGEN-TRANSFER, PHOSPHINE-BORANE, DEHYDROGENATION, CHEMISTRY, MECHANISM, PRECURSOR, STORAGE",

author = "Stubbs, \{Naomi E.\} and Titel Jurca and Leitao, \{Erin M.\} and Woodall, \{Christopher H.\} and Ian Manners",

year = "2013",

doi = "10.1039/c3cc44373f",

language = "English",

volume = "49",

pages = "9098--9100",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "80",

}

TY - JOUR

T1 - Polyaminoborane main chain scission using N-heterocyclic carbenes; formation of donor-stabilised monomeric aminoboranes

AU - Stubbs, Naomi E.

AU - Jurca, Titel

AU - Leitao, Erin M.

AU - Woodall, Christopher H.

AU - Manners, Ian

PY - 2013

Y1 - 2013

N2 - The reaction of N-heterocyclic carbenes with polyaminoboranes [MeNH-BH2](n) or [NH2-BH2](n) at 20 degrees C led to depolymerisation and the formation of labile, monomeric aminoborane-NHC adducts, RNH-BH2-NHC (R = Me or H); a similar NHC adduct of Ph2N=BCl2 was characterized by single crystal X-ray diffraction.

AB - The reaction of N-heterocyclic carbenes with polyaminoboranes [MeNH-BH2](n) or [NH2-BH2](n) at 20 degrees C led to depolymerisation and the formation of labile, monomeric aminoborane-NHC adducts, RNH-BH2-NHC (R = Me or H); a similar NHC adduct of Ph2N=BCl2 was characterized by single crystal X-ray diffraction.

KW - MOLECULAR-WEIGHT POLYAMINOBORANES

KW - AMINE-BORANE ADDUCTS

KW - AMMONIA-BORANE

KW - HYDROGEN-TRANSFER

KW - PHOSPHINE-BORANE

KW - DEHYDROGENATION

KW - CHEMISTRY

KW - MECHANISM

KW - PRECURSOR

KW - STORAGE

U2 - 10.1039/c3cc44373f

DO - 10.1039/c3cc44373f

M3 - Article (Academic Journal)

C2 - 23982163

SN - 1359-7345

VL - 49

SP - 9098

EP - 9100

JO - Chemical Communications

JF - Chemical Communications

IS - 80

ER -

Polyaminoborane main chain scission using N-heterocyclic carbenes; formation of donor-stabilised monomeric aminoboranes

Abstract

Keywords

Access to Document

Handle.net

Fingerprint

Projects

Catalytic Dehydrocoupling of Amine-Borane Adducts: A Route to Polyaminoboranes, Boron-Nitrogen Analogues of Polyolefins

Cite this