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Polynuclear Complexes as Precursor Templates for Hierarchical Microporous Graphitic Carbon: An Unusual Approach

Research output: Contribution to journalArticle

Original languageEnglish
Pages (from-to)25967-25971
Number of pages5
JournalACS Applied Materials and Interfaces
Volume10
Issue number31
Early online date17 Jul 2018
DOIs
DateAccepted/In press - 17 Jul 2018
DateE-pub ahead of print - 17 Jul 2018
DatePublished (current) - 8 Aug 2018

Abstract

A highly porous carbon was synthesised using a coordination complex as an unusual precursor. During controlled pyrolysis a trinuclear copper complex, [CuII
3Cl4(H2L)2]•CH3OH, undergoes phase changes with melt and expulsion of different gases to produce a unique morphology of copper-doped carbon which, upon acid treatment, produces highly porous graphitic carbon with a surface area of 857 m2g-1 and a gravimetric hydrogen uptake of 1.1 wt% at 0.5 bar pressure at 77 K.

    Research areas

  • complex-derived carbon, coordination complex, graphitic carbon, hydrogen storage, polynuclear complex, porous carbon, template precursor

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  • Full-text PDF (accepted author manuscript)

    Rights statement: This is the author accepted manuscript (AAM). The final published version (version of record) is available online via ACS at https://pubs.acs.org/doi/10.1021/acsami.8b10149 . Please refer to any applicable terms of use of the publisher.

    Accepted author manuscript, 755 KB, PDF document

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