Prochiral Guanine Adsorption on Au(111): An Entropy-Stabilized Intermixed Guanine-Quartet Chiral Structure

W Xu; R.E.A. Kelly; H Gersen; E Laegsgaard; I Stensgaard; L.N. Kantorovich; F Besenbacher

doi:10.1002/smll.200900315

Prochiral Guanine Adsorption on Au(111): An Entropy-Stabilized Intermixed Guanine-Quartet Chiral Structure

W Xu
, R.E.A. Kelly
, H Gersen
, E Laegsgaard
, I Stensgaard
, L.N. Kantorovich
, F Besenbacher

School of Physics

Research output: Contribution to journal › Article (Academic Journal) › peer-review

63 Citations (Scopus)

Abstract

Guanine molecules adsorbed on the Au(111) surface at room temperature are observed to form a heterochiral phase consisting of two homochiral G-quartet networks (see image, left). By annealing the sample at 400 K the R and L homochiral G-quartet networks are found to irreversibly transform to a heterochiral G-quartet network including both R and L G-quartets in an equal amount (see image, right).

Translated title of the contribution	Prochiral Guanine Adsorption on Au(111): An Entropy-Stabilized Intermixed Guanine-Quartet Chiral Structure
Original language	English
Pages (from-to)	1952 - 1956
Number of pages	5
Journal	Small
Volume	5
Issue number	17
DOIs	https://doi.org/10.1002/smll.200900315
Publication status	Published - Sept 2009

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Publisher: Wiley-VCH

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http://onlinelibrary.wiley.com/doi/10.1002/smll.200900315/abstract

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title = "Prochiral Guanine Adsorption on Au(111): An Entropy-Stabilized Intermixed Guanine-Quartet Chiral Structure",

abstract = "Guanine molecules adsorbed on the Au(111) surface at room temperature are observed to form a heterochiral phase consisting of two homochiral G-quartet networks (see image, left). By annealing the sample at 400 K the R and L homochiral G-quartet networks are found to irreversibly transform to a heterochiral G-quartet network including both R and L G-quartets in an equal amount (see image, right).",

author = "W Xu and R.E.A. Kelly and H Gersen and E Laegsgaard and I Stensgaard and L.N. Kantorovich and F Besenbacher",

note = "Publisher: Wiley-VCH",

year = "2009",

month = sep,

doi = "10.1002/smll.200900315",

language = "English",

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pages = "1952 -- 1956",

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TY - JOUR

T1 - Prochiral Guanine Adsorption on Au(111): An Entropy-Stabilized Intermixed Guanine-Quartet Chiral Structure

AU - Xu, W

AU - Kelly, R.E.A.

AU - Gersen, H

AU - Laegsgaard, E

AU - Stensgaard, I

AU - Kantorovich, L.N.

AU - Besenbacher, F

N1 - Publisher: Wiley-VCH

PY - 2009/9

Y1 - 2009/9

N2 - Guanine molecules adsorbed on the Au(111) surface at room temperature are observed to form a heterochiral phase consisting of two homochiral G-quartet networks (see image, left). By annealing the sample at 400 K the R and L homochiral G-quartet networks are found to irreversibly transform to a heterochiral G-quartet network including both R and L G-quartets in an equal amount (see image, right).

AB - Guanine molecules adsorbed on the Au(111) surface at room temperature are observed to form a heterochiral phase consisting of two homochiral G-quartet networks (see image, left). By annealing the sample at 400 K the R and L homochiral G-quartet networks are found to irreversibly transform to a heterochiral G-quartet network including both R and L G-quartets in an equal amount (see image, right).

U2 - 10.1002/smll.200900315

DO - 10.1002/smll.200900315

M3 - Article (Academic Journal)

C2 - 19437463

SN - 1613-6810

VL - 5

SP - 1952

EP - 1956

JO - Small

JF - Small

IS - 17

ER -

Prochiral Guanine Adsorption on Au(111): An Entropy-Stabilized Intermixed Guanine-Quartet Chiral Structure

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