Re-evaluation of the lifetimes of the major CFCs and CH3CCl3 using atmospheric trends

M. Rigby*, R. G. Prinn, S. O'Doherty, S. A. Montzka, Archibald McCulloch, C. M. Harth, J. Muehle, P. K. Salameh, R. F. Weiss, T Young, P. G. Simmonds, B. D. Hall, G. S. Dutton, D. Nance, D. J. Mondeel, J. W. Elkins, P. B. Krummel, L. P. Steele, P. J. Fraser

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)

Abstract

Since the Montreal Protocol on Substances that Deplete the Ozone Layer and its amendments came into effect, growth rates of the major ozone depleting substances (ODS), particularly CFC-11, -12 and -113 and CH3CCl3, have declined markedly, paving the way for global stratospheric ozone recovery. Emissions have now fallen to relatively low levels, therefore the rate at which this recovery occurs will depend largely on the atmospheric lifetime of these compounds. The first ODS measurements began in the early 1970s along with the first lifetime estimates calculated by considering their atmospheric trends. We now have global mole fraction records spanning multiple decades, prompting this lifetime re-evaluation. Using surface measurements from the Advanced Global Atmospheric Gases Experiment (AGAGE) and the National Oceanic and Atmospheric Administration Global Monitoring Division (NOAA GMD) from 1978 to 2011, we estimated the lifetime of CFC-11, CFC-12, CFC-113 and CH3CCl3 using a multi-species inverse method. A steady-state lifetime of 45 yr for CFC-11, currently recommended in the most recent World Meteorological Organisation (WMO) Scientific Assessments of Ozone Depletion, lies towards the lower uncertainty bound of our estimates, which are 54(48)(61) yr (1-sigma uncertainty) when AGAGE data were used and 52(45)(61) yr when the NOAA net-work data were used. Our derived lifetime for CFC-113 is significantly higher than the WMO estimates of 85 yr, being 109(99)(121) (AGAGE) and 109(97)(124) (NOAA). New estimates of the steady-state lifetimes of CFC-12 and CH3CCl3 are consistent with the current WMO recommendations, being 111(95)(132) and 112(95)(136) yr (CFC-12, AGAGE and NOAA respectively) and 5.04(4.92)(5.20) and 5.04(4.87)(5.23) yr (CH3CCl3, AGAGE and NOAA respectively).

Original languageEnglish
Pages (from-to)2691-2702
Number of pages12
JournalAtmospheric Chemistry and Physics
Volume13
Issue number5
DOIs
Publication statusPublished - 2013

Keywords

  • HYDROXYL RADICALS
  • TROPOSPHERIC OH
  • 2 DECADES
  • VARIABILITY
  • OZONE
  • GASES
  • HYDROCARBONS
  • METHODOLOGY
  • HALOCARBONS
  • CHLOROFORM

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Cite this

Rigby, M., Prinn, R. G., O'Doherty, S., Montzka, S. A., McCulloch, A., Harth, C. M., Muehle, J., Salameh, P. K., Weiss, R. F., Young, T., Simmonds, P. G., Hall, B. D., Dutton, G. S., Nance, D., Mondeel, D. J., Elkins, J. W., Krummel, P. B., Steele, L. P., & Fraser, P. J. (2013). Re-evaluation of the lifetimes of the major CFCs and CH3CCl3 using atmospheric trends. Atmospheric Chemistry and Physics, 13(5), 2691-2702. https://doi.org/10.5194/acp-13-2691-2013