Reactivity of a triruthenium acetylide complex towards alkynes and the silica-mediated dehydration of cluster-bound alkynols; X-ray crystal structures of the novel butadienyl species [Ru3(CO)8{μ3-η8-C(But)=CC(Ph)=C(H)Ph}] and the unusual complex [Ru3(CO)5(μ-CO){μ3-η5-CC(But)OC(Ph)2CCH}{μ3-η6-CHC(CPh2OH)COC(CPh2)CH}]

JPH Charmant; G Davies; PJ King; JR Wigginton; E Sappa

Reactivity of a triruthenium acetylide complex towards alkynes and the silica-mediated dehydration of cluster-bound alkynols; X-ray crystal structures of the novel butadienyl species [Ru₃(CO)₈{μ₃-η⁸-C(Bu^t)=CC(Ph)=C(H)Ph}] and the unusual complex [Ru₃(CO)₅(μ-CO){μ₃-η⁵-CC(Bu^t)OC(Ph)₂CCH}{μ₃-η⁶-CHC(CPh₂OH)COC(CPh₂)CH}]

JPH Charmant, G Davies, PJ King, JR Wigginton, E Sappa

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

Translated title of the contribution	Reactivity of a triruthenium acetylide complex towards alkynes and the silica-mediated dehydration of cluster-bound alkynols; X-ray crystal structures of the novel butadienyl species [Ru₃(CO)₈{μ₃-η⁸-C(Bu^t)=CC(Ph)=C(H)Ph}] and the unusual complex [Ru₃(CO)₅(μ-CO){μ₃-η⁵-CC(Bu^t)OC(Ph)₂CCH}{μ₃-η⁶-CHC(CPh₂OH)COC(CPh₂)CH}]
Original language	English
Pages (from-to)	2330 - 2340
Journal	Organometallics
Volume	19
Publication status	Published - 2000

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Charmant, JPH., Davies, G., King, PJ., Wigginton, JR., & Sappa, E. (2000). Reactivity of a triruthenium acetylide complex towards alkynes and the silica-mediated dehydration of cluster-bound alkynols; X-ray crystal structures of the novel butadienyl species [Ru₃(CO)₈{μ₃-η⁸-C(Bu^t)=CC(Ph)=C(H)Ph}] and the unusual complex [Ru₃(CO)₅(μ-CO){μ₃-η⁵-CC(Bu^t)OC(Ph)₂CCH}{μ₃-η⁶-CHC(CPh₂OH)COC(CPh₂)CH}]. Organometallics, 19, 2330 - 2340.

Charmant, JPH ; Davies, G ; King, PJ et al. / Reactivity of a triruthenium acetylide complex towards alkynes and the silica-mediated dehydration of cluster-bound alkynols; X-ray crystal structures of the novel butadienyl species [Ru₃(CO)₈{μ₃-η⁸-C(Bu^t)=CC(Ph)=C(H)Ph}] and the unusual complex [Ru₃(CO)₅(μ-CO){μ₃-η⁵-CC(Bu^t)OC(Ph)₂CCH}{μ₃-η⁶-CHC(CPh₂OH)COC(CPh₂)CH}]. In: Organometallics. 2000 ; Vol. 19. pp. 2330 - 2340.

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title = "Reactivity of a triruthenium acetylide complex towards alkynes and the silica-mediated dehydration of cluster-bound alkynols; X-ray crystal structures of the novel butadienyl species [Ru3(CO)8\{μ3-η8-C(But)=CC(Ph)=C(H)Ph\}] and the unusual complex [Ru3(CO)5(μ-CO)\{μ3-η5-CC(But)OC(Ph)2CCH\}\{μ3-η6-CHC(CPh2OH)COC(CPh2)CH\}]",

author = "JPH Charmant and G Davies and PJ King and JR Wigginton and E Sappa",

year = "2000",

language = "English",

volume = "19",

pages = "2330 -- 2340",

journal = "Organometallics",

issn = "1520-6041",

publisher = "American Chemical Society",

}

Charmant, JPH, Davies, G, King, PJ, Wigginton, JR & Sappa, E 2000, 'Reactivity of a triruthenium acetylide complex towards alkynes and the silica-mediated dehydration of cluster-bound alkynols; X-ray crystal structures of the novel butadienyl species [Ru₃(CO)₈{μ₃-η⁸-C(Bu^t)=CC(Ph)=C(H)Ph}] and the unusual complex [Ru₃(CO)₅(μ-CO){μ₃-η⁵-CC(Bu^t)OC(Ph)₂CCH}{μ₃-η⁶-CHC(CPh₂OH)COC(CPh₂)CH}]', Organometallics, vol. 19, pp. 2330 - 2340.

Reactivity of a triruthenium acetylide complex towards alkynes and the silica-mediated dehydration of cluster-bound alkynols; X-ray crystal structures of the novel butadienyl species [Ru₃(CO)₈{μ₃-η⁸-C(Bu^t)=CC(Ph)=C(H)Ph}] and the unusual complex [Ru₃(CO)₅(μ-CO){μ₃-η⁵-CC(Bu^t)OC(Ph)₂CCH}{μ₃-η⁶-CHC(CPh₂OH)COC(CPh₂)CH}]. / Charmant, JPH; Davies, G; King, PJ et al.
In: Organometallics, Vol. 19, 2000, p. 2330 - 2340.

Research output: Contribution to journal › Article (Academic Journal) › peer-review

TY - JOUR

T1 - Reactivity of a triruthenium acetylide complex towards alkynes and the silica-mediated dehydration of cluster-bound alkynols; X-ray crystal structures of the novel butadienyl species [Ru3(CO)8{μ3-η8-C(But)=CC(Ph)=C(H)Ph}] and the unusual complex [Ru3(CO)5(μ-CO){μ3-η5-CC(But)OC(Ph)2CCH}{μ3-η6-CHC(CPh2OH)COC(CPh2)CH}]

AU - Charmant, JPH

AU - Davies, G

AU - King, PJ

AU - Wigginton, JR

AU - Sappa, E

PY - 2000

Y1 - 2000

M3 - Article (Academic Journal)

SN - 1520-6041

VL - 19

SP - 2330

EP - 2340

JO - Organometallics

JF - Organometallics

ER -

Charmant JPH, Davies G, King PJ, Wigginton JR, Sappa E. Reactivity of a triruthenium acetylide complex towards alkynes and the silica-mediated dehydration of cluster-bound alkynols; X-ray crystal structures of the novel butadienyl species [Ru₃(CO)₈{μ₃-η⁸-C(Bu^t)=CC(Ph)=C(H)Ph}] and the unusual complex [Ru₃(CO)₅(μ-CO){μ₃-η⁵-CC(Bu^t)OC(Ph)₂CCH}{μ₃-η⁶-CHC(CPh₂OH)COC(CPh₂)CH}]. Organometallics. 2000;19:2330 - 2340.