Reagent-controlled lithiation–borylation

Daniele Leonori, Varinder K. Aggarwal*

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

15 Citations (Scopus)

Abstract

This chapter focuses on the stereo-controlled homologation of chiral boronic esters with chiral lithium carbenoid (lithiation–borylation) as a powerful method for the asymmetric synthesis of many complex molecules. It is highlighted that the potential methodology to create multiple contiguous stereogenic centers on “growing” carbon chains.

Original languageEnglish
Pages (from-to)271-295
Number of pages25
JournalTopics in Organometallic Chemistry
Volume49
DOIs
Publication statusPublished - 1 Jan 2015

Keywords

  • 1,2-metallate rearrangement
  • Boronic esters
  • Homologation
  • Lithiated carbamates
  • Stereospecific
  • Total synthesis

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