Reagent-controlled lithiation–borylation

Daniele Leonori; Varinder K. Aggarwal

doi:10.1007/978-3-319-13054-5_9

Reagent-controlled lithiation–borylation

Daniele Leonori, Varinder K. Aggarwal^*

^*Corresponding author for this work

Research output: Contribution to journal › Article (Academic Journal) › peer-review

29 Citations (Scopus)

Abstract

This chapter focuses on the stereo-controlled homologation of chiral boronic esters with chiral lithium carbenoid (lithiation–borylation) as a powerful method for the asymmetric synthesis of many complex molecules. It is highlighted that the potential methodology to create multiple contiguous stereogenic centers on “growing” carbon chains.

Original language	English
Pages (from-to)	271-295
Number of pages	25
Journal	Topics in Organometallic Chemistry
Volume	49
DOIs	https://doi.org/10.1007/978-3-319-13054-5_9
Publication status	Published - 1 Jan 2015

Research Groups and Themes

Organic & Biological

Keywords

1,2-metallate rearrangement
Boronic esters
Homologation
Lithiated carbamates
Stereospecific
Total synthesis

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10.1007/978-3-319-13054-5_9

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Cite this

@article{f761030196544024af5c9908b67488e0,

title = "Reagent-controlled lithiation–borylation",

abstract = "This chapter focuses on the stereo-controlled homologation of chiral boronic esters with chiral lithium carbenoid (lithiation–borylation) as a powerful method for the asymmetric synthesis of many complex molecules. It is highlighted that the potential methodology to create multiple contiguous stereogenic centers on “growing” carbon chains.",

keywords = "1,2-metallate rearrangement, Boronic esters, Homologation, Lithiated carbamates, Stereospecific, Total synthesis",

author = "Daniele Leonori and Aggarwal, \{Varinder K.\}",

year = "2015",

month = jan,

day = "1",

doi = "10.1007/978-3-319-13054-5\_9",

language = "English",

volume = "49",

pages = "271--295",

journal = "Topics in Organometallic Chemistry",

issn = "1436-6002",

publisher = "Springer Verlag",

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TY - JOUR

T1 - Reagent-controlled lithiation–borylation

AU - Leonori, Daniele

AU - Aggarwal, Varinder K.

PY - 2015/1/1

Y1 - 2015/1/1

N2 - This chapter focuses on the stereo-controlled homologation of chiral boronic esters with chiral lithium carbenoid (lithiation–borylation) as a powerful method for the asymmetric synthesis of many complex molecules. It is highlighted that the potential methodology to create multiple contiguous stereogenic centers on “growing” carbon chains.

AB - This chapter focuses on the stereo-controlled homologation of chiral boronic esters with chiral lithium carbenoid (lithiation–borylation) as a powerful method for the asymmetric synthesis of many complex molecules. It is highlighted that the potential methodology to create multiple contiguous stereogenic centers on “growing” carbon chains.

KW - 1,2-metallate rearrangement

KW - Boronic esters

KW - Homologation

KW - Lithiated carbamates

KW - Stereospecific

KW - Total synthesis

UR - https://www.scopus.com/pages/publications/84924354198

U2 - 10.1007/978-3-319-13054-5_9

DO - 10.1007/978-3-319-13054-5_9

M3 - Article (Academic Journal)

AN - SCOPUS:84924354198

SN - 1436-6002

VL - 49

SP - 271

EP - 295

JO - Topics in Organometallic Chemistry

JF - Topics in Organometallic Chemistry

ER -

Reagent-controlled lithiation–borylation

Abstract

Research Groups and Themes

Keywords

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Changing the Synthesis Landscape with Boron at the Helm: from Chiral Organometallics to Assembly Line Synthesis

Cite this

Reagent-controlled lithiation–borylation

Abstract

Research Groups and Themes

Keywords

Access to Document

Handle.net

Other files and links

Fingerprint

Projects

Changing the Synthesis Landscape with Boron at the Helm: from Chiral Organometallics to Assembly Line Synthesis

Cite this