Relaying stereochemistry through aromatic ureas: 1,9 and 1,15 remote stereocontrol

Jonathan Clayden; Mark Pickworth; Lyn H. Jones

doi:10.1039/b817527f

Relaying stereochemistry through aromatic ureas: 1,9 and 1,15 remote stereocontrol

Jonathan Clayden^*, Mark Pickworth, Lyn H. Jones

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

27 Citations (Scopus)

Abstract

The well-defined conformation of an N,N′-diarylurea allows a chiral sulfinyl substituent to influence diastereoselectivity in the formation of new stereogenic centres up to 14 bond lengths away.

Original language	English
Pages (from-to)	547-549
Number of pages	3
Journal	Chemical Communications
Issue number	5
Early online date	26 Nov 2008
DOIs	https://doi.org/10.1039/b817527f
Publication status	Published - 7 Feb 2009

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title = "Relaying stereochemistry through aromatic ureas: 1,9 and 1,15 remote stereocontrol",

abstract = "The well-defined conformation of an N,N′-diarylurea allows a chiral sulfinyl substituent to influence diastereoselectivity in the formation of new stereogenic centres up to 14 bond lengths away.",

author = "Jonathan Clayden and Mark Pickworth and Jones, {Lyn H.}",

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AU - Pickworth, Mark

AU - Jones, Lyn H.

PY - 2009/2/7

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N2 - The well-defined conformation of an N,N′-diarylurea allows a chiral sulfinyl substituent to influence diastereoselectivity in the formation of new stereogenic centres up to 14 bond lengths away.

AB - The well-defined conformation of an N,N′-diarylurea allows a chiral sulfinyl substituent to influence diastereoselectivity in the formation of new stereogenic centres up to 14 bond lengths away.

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M3 - Article (Academic Journal)

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SP - 547

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JO - Chemical Communications

JF - Chemical Communications

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Relaying stereochemistry through aromatic ureas: 1,9 and 1,15 remote stereocontrol

Abstract

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