Remote conformational responses to enantiomeric excess in carboxylate-binding dynamic foldamers

Natasha Eccles, Bryden A.F. Le Bailly, Flavio Della Sala, Iñigo J. Vitórica-Yrezábal, Jonathan Clayden, Simon J. Webb

Research output: Contribution to journalArticle (Academic Journal)

4 Citations (Scopus)
12 Downloads (Pure)

Abstract

A crystallographically characterised zinc(ii)-capped foldamer can sense the enantiomeric excess of scalemic carboxylate solutions, including those produced by enantioselective organocatalysis, and can relay this input signal along the foldamer body to a remote glycinamide group, which then provides an NMR spectroscopic output.

Original languageEnglish
Pages (from-to)9331-9334
Number of pages4
JournalChemical communications (Cambridge, England)
Volume55
Issue number63
Early online date8 Jul 2019
DOIs
Publication statusPublished - 14 Aug 2019

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