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Abstract
Under Rh-catalyzed conditions, typically electrophilic 1,4-benzoquinones exhibit nucleophilic reactivity, such that exposure to appropriate electrophiles generates products of C-H iodination, bromination, and phenylselenation. This provides a mild and general method for direct halofunctionalization, and the first method that can achieve direct C-H phenylselenation of this compound class. The scope and limitations of the new protocols are outlined, and representative derivatizations are highlighted.
Original language | English |
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Pages (from-to) | 4454-4457 |
Number of pages | 4 |
Journal | Organic Letters |
Volume | 18 |
Issue number | 18 |
Early online date | 7 Sep 2016 |
DOIs | |
Publication status | Published - 16 Sep 2016 |
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Projects
- 2 Finished