Self-sorted Oligophenylvinylene and Perylene Bisimide Hydrogels

Ana M. Castilla; Emily R. Draper; Michael C. Nolan; Christopher Brasnett; Annela Seddon; Laura L E Mears; Nathan Cowieson; Dave J. Adams

doi:10.1038/s41598-017-08644-0

Self-sorted Oligophenylvinylene and Perylene Bisimide Hydrogels

Ana M. Castilla
, Emily R. Draper
, Michael C. Nolan
, Christopher Brasnett
, Annela Seddon
, Laura L E Mears
, Nathan Cowieson
, Dave J. Adams^*

^*Corresponding author for this work

Research output: Contribution to journal › Article (Academic Journal) › peer-review

32 Citations (Scopus)

417 Downloads (Pure)

Abstract

We describe two component hydrogels with networks composed of self-sorted fibres. The component gelators are based on 1,4-distyrylbenzene (OPV3) and perylene bisimide (PBI) units. Self-sorted gels can be formed by a slow decrease in pH, which leads to sequential assembly. We demonstrate self-sorting by NMR, rheology and small angle X-ray scattering (SAXS). Photoconductive xerogels can be prepared by drying these gels. The wavelength response of the xerogel is different to that of the PBI alone.

Original language	English
Article number	8380
Number of pages	10
Journal	Scientific Reports
Volume	7
DOIs	https://doi.org/10.1038/s41598-017-08644-0
Publication status	Published - 21 Aug 2017

Keywords

Gels and hydrogels
Organic molecules in materials science

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10.1038/s41598-017-08644-0

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This is the final published version of the article (version of record). It first appeared online via Nature at https://www.nature.com/articles/s41598-017-08644-0. Please refer to any applicable terms of use of the publisher.
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This is the final published version of the article (version of record). It first appeared online via Nature at https://www.nature.com/articles/s41598-017-08644-0. Please refer to any applicable terms of use of the publisher.
Final published version, 1.54 MBLicence: CC BY

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title = "Self-sorted Oligophenylvinylene and Perylene Bisimide Hydrogels",

abstract = "We describe two component hydrogels with networks composed of self-sorted fibres. The component gelators are based on 1,4-distyrylbenzene (OPV3) and perylene bisimide (PBI) units. Self-sorted gels can be formed by a slow decrease in pH, which leads to sequential assembly. We demonstrate self-sorting by NMR, rheology and small angle X-ray scattering (SAXS). Photoconductive xerogels can be prepared by drying these gels. The wavelength response of the xerogel is different to that of the PBI alone.",

keywords = "Gels and hydrogels, Organic molecules in materials science",

author = "Castilla, \{Ana M.\} and Draper, \{Emily R.\} and Nolan, \{Michael C.\} and Christopher Brasnett and Annela Seddon and Mears, \{Laura L E\} and Nathan Cowieson and Adams, \{Dave J.\}",

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doi = "10.1038/s41598-017-08644-0",

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T1 - Self-sorted Oligophenylvinylene and Perylene Bisimide Hydrogels

AU - Castilla, Ana M.

AU - Draper, Emily R.

AU - Nolan, Michael C.

AU - Brasnett, Christopher

AU - Seddon, Annela

AU - Mears, Laura L E

AU - Cowieson, Nathan

AU - Adams, Dave J.

PY - 2017/8/21

Y1 - 2017/8/21

N2 - We describe two component hydrogels with networks composed of self-sorted fibres. The component gelators are based on 1,4-distyrylbenzene (OPV3) and perylene bisimide (PBI) units. Self-sorted gels can be formed by a slow decrease in pH, which leads to sequential assembly. We demonstrate self-sorting by NMR, rheology and small angle X-ray scattering (SAXS). Photoconductive xerogels can be prepared by drying these gels. The wavelength response of the xerogel is different to that of the PBI alone.

AB - We describe two component hydrogels with networks composed of self-sorted fibres. The component gelators are based on 1,4-distyrylbenzene (OPV3) and perylene bisimide (PBI) units. Self-sorted gels can be formed by a slow decrease in pH, which leads to sequential assembly. We demonstrate self-sorting by NMR, rheology and small angle X-ray scattering (SAXS). Photoconductive xerogels can be prepared by drying these gels. The wavelength response of the xerogel is different to that of the PBI alone.

KW - Gels and hydrogels

KW - Organic molecules in materials science

UR - https://www.scopus.com/pages/publications/85027871575

U2 - 10.1038/s41598-017-08644-0

DO - 10.1038/s41598-017-08644-0

M3 - Article (Academic Journal)

C2 - 28827598

AN - SCOPUS:85027871575

SN - 2045-2322

VL - 7

JO - Scientific Reports

JF - Scientific Reports

M1 - 8380

ER -

Self-sorted Oligophenylvinylene and Perylene Bisimide Hydrogels

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