Separation of phobane isomers by selective protonation

M R  Eberhard; E  Carrington-Smith; E E  Drent; P S  Marsh; A G  Orpen; H  Phetmung; P G  Pringle

doi:10.1002/adsc.200505073

Separation of phobane isomers by selective protonation

M R Eberhard, E Carrington-Smith, E E Drent, P S Marsh, A G Orpen, H Phetmung, P G Pringle

Research output: Contribution to journal › Article (Academic Journal) › peer-review

22 Citations (Scopus)

Abstract

The industrially important mixture of sym-and asym-phobanes are separated efficiently by selective protonation of the sym isomer with hydrochloric acid; carbonylation catalysts generated from diphosphanes derived from the separated isomers have quite different activities and product selectivities.

Original language	English
Pages (from-to)	1345-1348
Number of pages	4
Journal	Advanced Synthesis and Catalysis
Volume	347
Issue number	10
DOIs	https://doi.org/10.1002/adsc.200505073
Publication status	Published - Aug 2005

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title = "Separation of phobane isomers by selective protonation",

abstract = "The industrially important mixture of sym-and asym-phobanes are separated efficiently by selective protonation of the sym isomer with hydrochloric acid; carbonylation catalysts generated from diphosphanes derived from the separated isomers have quite different activities and product selectivities.",

author = "Eberhard, {M R} and E Carrington-Smith and Drent, {E E} and Marsh, {P S} and Orpen, {A G} and H Phetmung and Pringle, {P G}",

year = "2005",

month = aug,

doi = "10.1002/adsc.200505073",

language = "English",

volume = "347",

pages = "1345--1348",

journal = "Advanced Synthesis and Catalysis",

issn = "1615-4150",

publisher = "Wiley-VCH Verlag",

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T1 - Separation of phobane isomers by selective protonation

AU - Eberhard, M R

AU - Carrington-Smith, E

AU - Drent, E E

AU - Marsh, P S

AU - Orpen, A G

AU - Phetmung, H

AU - Pringle, P G

PY - 2005/8

Y1 - 2005/8

N2 - The industrially important mixture of sym-and asym-phobanes are separated efficiently by selective protonation of the sym isomer with hydrochloric acid; carbonylation catalysts generated from diphosphanes derived from the separated isomers have quite different activities and product selectivities.

AB - The industrially important mixture of sym-and asym-phobanes are separated efficiently by selective protonation of the sym isomer with hydrochloric acid; carbonylation catalysts generated from diphosphanes derived from the separated isomers have quite different activities and product selectivities.

U2 - 10.1002/adsc.200505073

DO - 10.1002/adsc.200505073

M3 - Article (Academic Journal)

VL - 347

SP - 1345

EP - 1348

JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

SN - 1615-4150

IS - 10

ER -

Separation of phobane isomers by selective protonation

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