Projects per year
Abstract
A scalable and operationally simple synthesis of trisubstituted alkenyl boronic esters has been achieved using a Zr-catalyzed carboalumination of terminal alkynes followed by in situ transmetalation with i-PrOBpin. The products are formed in good yields and with excellent regioselectivity and perfect stereoselectivity. The new procedure provides a significant improvement over the previously reported syntheses.
Original language | English |
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Pages (from-to) | 3136-3139 |
Number of pages | 4 |
Journal | Organic Letters |
Volume | 20 |
Issue number | 10 |
Early online date | 9 May 2018 |
DOIs | |
Publication status | Published - 18 May 2018 |
Fingerprint Dive into the research topics of 'Stereo- and Regiocontrolled Methylboration of Terminal Alkynes'. Together they form a unique fingerprint.
Projects
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Changing the Synthesis Landscape with Boron at the Helm: from Chiral Organometallics to Assembly Line Synthesis
14/05/12 → 13/01/18
Project: Research