Stereochemical relays: Communication via conformation

Jonathan Clayden; Neoclis Vassiliou

doi:10.1039/b604548k

Stereochemical relays: Communication via conformation

Jonathan Clayden^*
, Neoclis Vassiliou

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

57 Citations (Scopus)

Abstract

Stereochemistry is information, and stereoselective reactions are the means by which that information may be communicated within and between molecules. The control of remote stereogenic centres can be achieved by stereochemical relay, and the use of thermodynamic control over conformational preference is turning out to be a very powerful method for long-range transmission of stereochemical information.

Original language	English
Pages (from-to)	2667-2678
Number of pages	12
Journal	Organic and Biomolecular Chemistry
Volume	4
Issue number	14
Early online date	25 May 2006
DOIs	https://doi.org/10.1039/b604548k
Publication status	Published - 21 Jul 2006

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Organic & Biological

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@article{1b25f7ceb7a64c68aa4c7501e8d7b744,

title = "Stereochemical relays: Communication via conformation",

abstract = "Stereochemistry is information, and stereoselective reactions are the means by which that information may be communicated within and between molecules. The control of remote stereogenic centres can be achieved by stereochemical relay, and the use of thermodynamic control over conformational preference is turning out to be a very powerful method for long-range transmission of stereochemical information.",

author = "Jonathan Clayden and Neoclis Vassiliou",

year = "2006",

month = jul,

day = "21",

doi = "10.1039/b604548k",

language = "English",

volume = "4",

pages = "2667--2678",

journal = "Organic and Biomolecular Chemistry",

issn = "1477-0520",

publisher = "Royal Society of Chemistry",

number = "14",

}

TY - JOUR

T1 - Stereochemical relays

T2 - Communication via conformation

AU - Clayden, Jonathan

AU - Vassiliou, Neoclis

PY - 2006/7/21

Y1 - 2006/7/21

N2 - Stereochemistry is information, and stereoselective reactions are the means by which that information may be communicated within and between molecules. The control of remote stereogenic centres can be achieved by stereochemical relay, and the use of thermodynamic control over conformational preference is turning out to be a very powerful method for long-range transmission of stereochemical information.

AB - Stereochemistry is information, and stereoselective reactions are the means by which that information may be communicated within and between molecules. The control of remote stereogenic centres can be achieved by stereochemical relay, and the use of thermodynamic control over conformational preference is turning out to be a very powerful method for long-range transmission of stereochemical information.

UR - https://www.scopus.com/pages/publications/33745852672

U2 - 10.1039/b604548k

DO - 10.1039/b604548k

M3 - Article (Academic Journal)

C2 - 16826289

AN - SCOPUS:33745852672

SN - 1477-0520

VL - 4

SP - 2667

EP - 2678

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 14

ER -

Stereochemical relays: Communication via conformation

Abstract

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