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Abstract
The use of a bifunctional cinchona/thiourea organocatalyst for the direct and α-stereoselective glycosylation of 2-nitrogalactals is demonstrated for the first time. The conditions are mild, practical, and applicable to a wide range of glycoside acceptors with products being isolated in good to excellent yields. The method is exemplified in the synthesis of mucin type Core 6 and 7 glycopeptides.
Original language | English |
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Pages (from-to) | 4222-4225 |
Number of pages | 4 |
Journal | Organic Letters |
Volume | 18 |
Issue number | 17 |
Early online date | 16 Aug 2016 |
DOIs | |
Publication status | Published - 2 Sep 2016 |
Structured keywords
- BCS and TECS CDTs
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- 3 Finished