Subtle effects of ligand backbone on the efficiency of iron-diphos catalysed Negishi cross-coupling reactions

Jamie Clifton; Evi R M Habraken; Paul G. Pringle; Ian Manners

doi:10.1039/c5cy00851d

Subtle effects of ligand backbone on the efficiency of iron-diphos catalysed Negishi cross-coupling reactions

Jamie Clifton, Evi R M Habraken, Paul G. Pringle^*, Ian Manners

^*Corresponding author for this work

Research output: Contribution to journal › Article (Academic Journal) › peer-review

10 Citations (Scopus)

Abstract

Substantially more active iron catalysts for a standard Negishi cross-coupling are obtained when bis(diarylphosphino)thiophenes are employed in place of the benchmark ligand bis(diphenylphosphino)benzene. The thiophene ligands have the advantages of ease of synthesis and ready modification.

Original language	English
Pages (from-to)	4350-4353
Number of pages	4
Journal	Catalysis Science and Technology
Volume	5
Issue number	9
DOIs	https://doi.org/10.1039/c5cy00851d
Publication status	Published - 13 Jul 2015

Research Groups and Themes

BCS and TECS CDTs

Access to Document

10.1039/c5cy00851d

Handle.net

Persistent link

Cite this

@article{ca054e9eaa7143e092ea42740c94bdba,

title = "Subtle effects of ligand backbone on the efficiency of iron-diphos catalysed Negishi cross-coupling reactions",

abstract = "Substantially more active iron catalysts for a standard Negishi cross-coupling are obtained when bis(diarylphosphino)thiophenes are employed in place of the benchmark ligand bis(diphenylphosphino)benzene. The thiophene ligands have the advantages of ease of synthesis and ready modification.",

author = "Jamie Clifton and Habraken, {Evi R M} and Pringle, {Paul G.} and Ian Manners",

year = "2015",

month = jul,

day = "13",

doi = "10.1039/c5cy00851d",

language = "English",

volume = "5",

pages = "4350--4353",

journal = "Catalysis Science and Technology",

issn = "2044-4753",

publisher = "Royal Society of Chemistry",

number = "9",

}

TY - JOUR

T1 - Subtle effects of ligand backbone on the efficiency of iron-diphos catalysed Negishi cross-coupling reactions

AU - Clifton, Jamie

AU - Habraken, Evi R M

AU - Pringle, Paul G.

AU - Manners, Ian

PY - 2015/7/13

Y1 - 2015/7/13

N2 - Substantially more active iron catalysts for a standard Negishi cross-coupling are obtained when bis(diarylphosphino)thiophenes are employed in place of the benchmark ligand bis(diphenylphosphino)benzene. The thiophene ligands have the advantages of ease of synthesis and ready modification.

AB - Substantially more active iron catalysts for a standard Negishi cross-coupling are obtained when bis(diarylphosphino)thiophenes are employed in place of the benchmark ligand bis(diphenylphosphino)benzene. The thiophene ligands have the advantages of ease of synthesis and ready modification.

UR - http://www.scopus.com/inward/record.url?scp=84939508980&partnerID=8YFLogxK

U2 - 10.1039/c5cy00851d

DO - 10.1039/c5cy00851d

M3 - Article (Academic Journal)

AN - SCOPUS:84939508980

SN - 2044-4753

VL - 5

SP - 4350

EP - 4353

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

IS - 9

ER -

Subtle effects of ligand backbone on the efficiency of iron-diphos catalysed Negishi cross-coupling reactions

Abstract

Research Groups and Themes

Access to Document

Handle.net

Other files and links

Fingerprint

3-month Core Capability for Chemistry Research

Cite this

Subtle effects of ligand backbone on the efficiency of iron-diphos catalysed Negishi cross-coupling reactions

Abstract

Research Groups and Themes

Access to Document

Handle.net

Other files and links

Fingerprint

Projects

3-month Core Capability for Chemistry Research

Cite this