Abstract
An efficient, classical resolution of the versatile P-ligand intermediate 6-phospha-2,4,8-trioxa-adamantane (CgPH) is described and the rhodium complex of the optically pure secondary phosphine beta-CgPH is an active and moderately selective asymmetric hydrogenation catalyst.
Original language | English |
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Pages (from-to) | 100-102 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 46 |
Issue number | 1 |
DOIs | |
Publication status | Published - 2010 |