Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis

Jonathan Hopewell; Piotr Jankowski; Claire L. McMullin; A. Guy Orpen; Paul G. Pringle

doi:10.1039/b916359j

Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis

Jonathan Hopewell
, Piotr Jankowski
, Claire L. McMullin
, A. Guy Orpen
, Paul G. Pringle

Research output: Contribution to journal › Article (Academic Journal) › peer-review

23 Citations (Scopus)

Abstract

An efficient, classical resolution of the versatile P-ligand intermediate 6-phospha-2,4,8-trioxa-adamantane (CgPH) is described and the rhodium complex of the optically pure secondary phosphine beta-CgPH is an active and moderately selective asymmetric hydrogenation catalyst.

Original language	English
Pages (from-to)	100-102
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	1
DOIs	https://doi.org/10.1039/b916359j
Publication status	Published - 2010

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Inorganic & Materials

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@article{b0f399a70939485980cb4c64e0cd0301,

title = "Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis",

abstract = "An efficient, classical resolution of the versatile P-ligand intermediate 6-phospha-2,4,8-trioxa-adamantane (CgPH) is described and the rhodium complex of the optically pure secondary phosphine beta-CgPH is an active and moderately selective asymmetric hydrogenation catalyst.",

author = "Jonathan Hopewell and Piotr Jankowski and McMullin, \{Claire L.\} and Orpen, \{A. Guy\} and Pringle, \{Paul G.\}",

year = "2010",

doi = "10.1039/b916359j",

language = "English",

volume = "46",

pages = "100--102",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "1",

}

Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis. / Hopewell, Jonathan; Jankowski, Piotr; McMullin, Claire L. et al.
In: Chemical Communications, Vol. 46, No. 1, 2010, p. 100-102.

Research output: Contribution to journal › Article (Academic Journal) › peer-review

TY - JOUR

T1 - Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis

AU - Hopewell, Jonathan

AU - Jankowski, Piotr

AU - McMullin, Claire L.

AU - Orpen, A. Guy

AU - Pringle, Paul G.

PY - 2010

Y1 - 2010

N2 - An efficient, classical resolution of the versatile P-ligand intermediate 6-phospha-2,4,8-trioxa-adamantane (CgPH) is described and the rhodium complex of the optically pure secondary phosphine beta-CgPH is an active and moderately selective asymmetric hydrogenation catalyst.

AB - An efficient, classical resolution of the versatile P-ligand intermediate 6-phospha-2,4,8-trioxa-adamantane (CgPH) is described and the rhodium complex of the optically pure secondary phosphine beta-CgPH is an active and moderately selective asymmetric hydrogenation catalyst.

U2 - 10.1039/b916359j

DO - 10.1039/b916359j

M3 - Article (Academic Journal)

C2 - 20024306

SN - 1359-7345

VL - 46

SP - 100

EP - 102

JO - Chemical Communications

JF - Chemical Communications

IS - 1

ER -

Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis

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