Synthesis and Applications of Rhodacyclopentanones Derived From C-C Bond Activation

Megan H Shaw; John Bower

doi:10.1039/C6CC04359C

Synthesis and Applications of Rhodacyclopentanones Derived From C-C Bond Activation

Megan H Shaw, John Bower

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

76 Citations (Scopus)

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Abstract

Rhodacyclopentanones, an “sp3-rich” class of metallacycle, underpin an emerging range of catalytic methodologies for the direct generation of complex scaffolds. This review highlights strategies for accessing rhodacyclopentanones (and related species) by C–C bond activation of cyclobutanones or cyclopropanes. The scope and mechanism of methodologies that exploit these activation modes is outlined.

Original language	English
Pages (from-to)	10817-10829
Number of pages	13
Journal	Chemical Communications
Volume	52
Issue number	72
Early online date	7 Jul 2016
DOIs	https://doi.org/10.1039/C6CC04359C
Publication status	Published - 18 Sept 2016

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A 13C NMR Coldprobe to Underpin Chemistry Research.
Butts, C. P. (Principal Investigator)
28/02/14 → 29/11/17
Project: Research
3-month Core Capability for Chemistry Research
Crosby, J. (Principal Investigator)
1/01/13 → 1/04/13
Project: Research

Cite this

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title = "Synthesis and Applications of Rhodacyclopentanones Derived From C-C Bond Activation",

abstract = "Rhodacyclopentanones, an “sp3-rich” class of metallacycle, underpin an emerging range of catalytic methodologies for the direct generation of complex scaffolds. This review highlights strategies for accessing rhodacyclopentanones (and related species) by C–C bond activation of cyclobutanones or cyclopropanes. The scope and mechanism of methodologies that exploit these activation modes is outlined.",

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AU - Bower, John

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AB - Rhodacyclopentanones, an “sp3-rich” class of metallacycle, underpin an emerging range of catalytic methodologies for the direct generation of complex scaffolds. This review highlights strategies for accessing rhodacyclopentanones (and related species) by C–C bond activation of cyclobutanones or cyclopropanes. The scope and mechanism of methodologies that exploit these activation modes is outlined.

U2 - 10.1039/C6CC04359C

DO - 10.1039/C6CC04359C

M3 - Article (Academic Journal)

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EP - 10829

JO - Chemical Communications

JF - Chemical Communications

IS - 72

ER -

Synthesis and Applications of Rhodacyclopentanones Derived From C-C Bond Activation

Abstract

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A 13C NMR Coldprobe to Underpin Chemistry Research.

3-month Core Capability for Chemistry Research

Cite this