Synthesis and characterisation of platinum(II)-bis(boryl) catalyst precursors for diboration of alkynes and diynes:  molecular structures of cis-[(PPh3)2Pt(Bcat)2],cis-[(dppe)Pt(Bcat)2],cis-[(dppb)Pt(Bcat)2],(E)-(4-MeOC6H4)C(Bcat)=CH(Bcat),(Z)-(C6H5)C(Bcat)=C(C6H5)(Bcat), and (Z,Z)-(4-MeOC6H4)C(BCat)=C(Bcat)C(Bcat)=C(4-MeOC6H4)(BCat) (cat=1,2-O2C6H4; dppe=Ph2PCH2CH2PPh2;

G Lesley; P Nguyen; NJ Taylor; TB Marder; AJ Scott; W Clegg; NC Norman

Synthesis and characterisation of platinum(II)-bis(boryl) catalyst precursors for diboration of alkynes and diynes: molecular structures of cis-[(PPh₃)₂Pt(Bcat)₂],cis-[(dppe)Pt(Bcat)₂],cis-[(dppb)Pt(Bcat)₂],(E)-(4-MeOC₆H₄)C(Bcat)=CH(Bcat),(Z)-(C₆H₅)C(Bcat)=C(C₆H₅)(Bcat), and (Z,Z)-(4-MeOC₆H₄)C(BCat)=C(Bcat)C(Bcat)=C(4-MeOC₆H₄)(BCat) (cat=1,2-O₂C₆H₄; dppe=Ph₂PCH₂CH₂PPh₂;

G Lesley
, P Nguyen
, NJ Taylor
, TB Marder
, AJ Scott
, W Clegg
, NC Norman

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

250 Citations (Scopus)

Translated title of the contribution	Synthesis and characterisation of platinum(II)-bis(boryl) catalyst precursors for diboration of alkynes and diynes: molecular structures of cis-[(PPh₃)₂Pt(Bcat)₂],cis-[(dppe)Pt(Bcat)₂],cis-[(dppb)Pt(Bcat)₂],(E)-(4-MeOC₆H₄)C(Bcat)=CH(Bcat),(Z)-(C₆H₅)C(Bcat)=C(C₆H₅)(Bcat), and (Z,Z)-(4-MeOC₆H₄)C(BCat)=C(Bcat)C(Bcat)=C(4-MeOC₆H₄)(BCat) (cat=1,2-O₂C₆H₄; dppe=Ph₂PCH₂CH₂PPh₂;
Original language	English
Pages (from-to)	5137 - 5154
Journal	Organometallics
Volume	15
Publication status	Published - 1996

Bibliographical note

Other: There is one more formula to go after the last semi-colon in the Title overflow: dppb=Ph2P(CH2)4PPh<sub.2

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Lesley, G., Nguyen, P., Taylor, NJ., Marder, TB., Scott, AJ., Clegg, W., & Norman, NC. (1996). Synthesis and characterisation of platinum(II)-bis(boryl) catalyst precursors for diboration of alkynes and diynes: molecular structures of cis-[(PPh₃)₂Pt(Bcat)₂],cis-[(dppe)Pt(Bcat)₂],cis-[(dppb)Pt(Bcat)₂],(E)-(4-MeOC₆H₄)C(Bcat)=CH(Bcat),(Z)-(C₆H₅)C(Bcat)=C(C₆H₅)(Bcat), and (Z,Z)-(4-MeOC₆H₄)C(BCat)=C(Bcat)C(Bcat)=C(4-MeOC₆H₄)(BCat) (cat=1,2-O₂C₆H₄; dppe=Ph₂PCH₂CH₂PPh₂; Organometallics, 15, 5137 - 5154.

Lesley, G ; Nguyen, P ; Taylor, NJ et al. / Synthesis and characterisation of platinum(II)-bis(boryl) catalyst precursors for diboration of alkynes and diynes: molecular structures of cis-[(PPh₃)₂Pt(Bcat)₂],cis-[(dppe)Pt(Bcat)₂],cis-[(dppb)Pt(Bcat)₂],(E)-(4-MeOC₆H₄)C(Bcat)=CH(Bcat),(Z)-(C₆H₅)C(Bcat)=C(C₆H₅)(Bcat), and (Z,Z)-(4-MeOC₆H₄)C(BCat)=C(Bcat)C(Bcat)=C(4-MeOC₆H₄)(BCat) (cat=1,2-O₂C₆H₄; dppe=Ph₂PCH₂CH₂PPh₂;. In: Organometallics. 1996 ; Vol. 15. pp. 5137 - 5154.

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title = "Synthesis and characterisation of platinum(II)-bis(boryl) catalyst precursors for diboration of alkynes and diynes: molecular structures of cis-[(PPh3)2Pt(Bcat)2],cis-[(dppe)Pt(Bcat)2],cis-[(dppb)Pt(Bcat)2],(E)-(4-MeOC6H4)C(Bcat)=CH(Bcat),(Z)-(C6H5)C(Bcat)=C(C6H5)(Bcat), and (Z,Z)-(4-MeOC6H4)C(BCat)=C(Bcat)C(Bcat)=C(4-MeOC6H4)(BCat) (cat=1,2-O2C6H4; dppe=Ph2PCH2CH2PPh2;",

author = "G Lesley and P Nguyen and NJ Taylor and TB Marder and AJ Scott and W Clegg and NC Norman",

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Lesley, G, Nguyen, P, Taylor, NJ, Marder, TB, Scott, AJ, Clegg, W & Norman, NC 1996, 'Synthesis and characterisation of platinum(II)-bis(boryl) catalyst precursors for diboration of alkynes and diynes: molecular structures of cis-[(PPh₃)₂Pt(Bcat)₂],cis-[(dppe)Pt(Bcat)₂],cis-[(dppb)Pt(Bcat)₂],(E)-(4-MeOC₆H₄)C(Bcat)=CH(Bcat),(Z)-(C₆H₅)C(Bcat)=C(C₆H₅)(Bcat), and (Z,Z)-(4-MeOC₆H₄)C(BCat)=C(Bcat)C(Bcat)=C(4-MeOC₆H₄)(BCat) (cat=1,2-O₂C₆H₄; dppe=Ph₂PCH₂CH₂PPh₂;', Organometallics, vol. 15, pp. 5137 - 5154.

Synthesis and characterisation of platinum(II)-bis(boryl) catalyst precursors for diboration of alkynes and diynes: molecular structures of cis-[(PPh₃)₂Pt(Bcat)₂],cis-[(dppe)Pt(Bcat)₂],cis-[(dppb)Pt(Bcat)₂],(E)-(4-MeOC₆H₄)C(Bcat)=CH(Bcat),(Z)-(C₆H₅)C(Bcat)=C(C₆H₅)(Bcat), and (Z,Z)-(4-MeOC₆H₄)C(BCat)=C(Bcat)C(Bcat)=C(4-MeOC₆H₄)(BCat) (cat=1,2-O₂C₆H₄; dppe=Ph₂PCH₂CH₂PPh₂; / Lesley, G; Nguyen, P; Taylor, NJ et al.
In: Organometallics, Vol. 15, 1996, p. 5137 - 5154.

Research output: Contribution to journal › Article (Academic Journal) › peer-review

TY - JOUR

T1 - Synthesis and characterisation of platinum(II)-bis(boryl) catalyst precursors for diboration of alkynes and diynes: molecular structures of cis-[(PPh3)2Pt(Bcat)2],cis-[(dppe)Pt(Bcat)2],cis-[(dppb)Pt(Bcat)2],(E)-(4-MeOC6H4)C(Bcat)=CH(Bcat),(Z)-(C6H5)C(Bcat)=C(C6H5)(Bcat), and (Z,Z)-(4-MeOC6H4)C(BCat)=C(Bcat)C(Bcat)=C(4-MeOC6H4)(BCat) (cat=1,2-O2C6H4; dppe=Ph2PCH2CH2PPh2;

AU - Lesley, G

AU - Nguyen, P

AU - Taylor, NJ

AU - Marder, TB

AU - Scott, AJ

AU - Clegg, W

AU - Norman, NC

N1 - Other: There is one more formula to go after the last semi-colon in the Title overflow: dppb=Ph2P(CH2)4PPh<sub.2

PY - 1996

Y1 - 1996

M3 - Article (Academic Journal)

SN - 1520-6041

VL - 15

SP - 5137

EP - 5154

JO - Organometallics

JF - Organometallics

ER -

Lesley G, Nguyen P, Taylor NJ, Marder TB, Scott AJ, Clegg W et al. Synthesis and characterisation of platinum(II)-bis(boryl) catalyst precursors for diboration of alkynes and diynes: molecular structures of cis-[(PPh₃)₂Pt(Bcat)₂],cis-[(dppe)Pt(Bcat)₂],cis-[(dppb)Pt(Bcat)₂],(E)-(4-MeOC₆H₄)C(Bcat)=CH(Bcat),(Z)-(C₆H₅)C(Bcat)=C(C₆H₅)(Bcat), and (Z,Z)-(4-MeOC₆H₄)C(BCat)=C(Bcat)C(Bcat)=C(4-MeOC₆H₄)(BCat) (cat=1,2-O₂C₆H₄; dppe=Ph₂PCH₂CH₂PPh₂; Organometallics. 1996;15:5137 - 5154.