Synthesis of epoxides from aldehydes and tosylhydrazone salts catalysed by triphenylarsine: complete trans selectivity for all combinations of coupling partners

VK Aggarwal; Mamta Patel; John Studley

doi:10.1039/b204252e

Synthesis of epoxides from aldehydes and tosylhydrazone salts catalysed by triphenylarsine: complete trans selectivity for all combinations of coupling partners

VK Aggarwal^*, Mamta Patel, John Studley

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

27 Citations (Scopus)

Abstract

Triphenylarsine catalyses the formation of epoxides from carbonyl compounds and tosylhydrazone salts. This convergent synthesis gives complete trans selectivity for all aldehyde and tosylhydrazone salt coupling partners.

Original language	English
Pages (from-to)	1514-1515
Number of pages	2
Journal	Chemical Communications
Issue number	14
DOIs	https://doi.org/10.1039/b204252e
Publication status	Published - 2002

Keywords

ARSONIUM YLIDES

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@article{645a24b9f4b0410bb7140986cac8d343,

title = "Synthesis of epoxides from aldehydes and tosylhydrazone salts catalysed by triphenylarsine: complete trans selectivity for all combinations of coupling partners",

abstract = "Triphenylarsine catalyses the formation of epoxides from carbonyl compounds and tosylhydrazone salts. This convergent synthesis gives complete trans selectivity for all aldehyde and tosylhydrazone salt coupling partners.",

keywords = "ARSONIUM YLIDES",

author = "VK Aggarwal and Mamta Patel and John Studley",

year = "2002",

doi = "10.1039/b204252e",

language = "English",

pages = "1514--1515",

journal = "Chemical Communications",

issn = "1364-548X",

publisher = "Royal Society of Chemistry",

number = "14",

}

TY - JOUR

T1 - Synthesis of epoxides from aldehydes and tosylhydrazone salts catalysed by triphenylarsine

T2 - complete trans selectivity for all combinations of coupling partners

AU - Aggarwal, VK

AU - Patel, Mamta

AU - Studley, John

PY - 2002

Y1 - 2002

N2 - Triphenylarsine catalyses the formation of epoxides from carbonyl compounds and tosylhydrazone salts. This convergent synthesis gives complete trans selectivity for all aldehyde and tosylhydrazone salt coupling partners.

AB - Triphenylarsine catalyses the formation of epoxides from carbonyl compounds and tosylhydrazone salts. This convergent synthesis gives complete trans selectivity for all aldehyde and tosylhydrazone salt coupling partners.

KW - ARSONIUM YLIDES

U2 - 10.1039/b204252e

DO - 10.1039/b204252e

M3 - Article (Academic Journal)

SN - 1364-548X

SP - 1514

EP - 1515

JO - Chemical Communications

JF - Chemical Communications

IS - 14

ER -

Synthesis of epoxides from aldehydes and tosylhydrazone salts catalysed by triphenylarsine: complete trans selectivity for all combinations of coupling partners

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