Synthesis of Highly Enantioenriched C-Tertiary Amines From Boronic Esters: Application to the Synthesis of Igmesine

Tim G. Elford; Varinder K. Aggarwal; Viktor Bahutski

doi:10.1002/anie.201006037

Synthesis of Highly Enantioenriched C-Tertiary Amines From Boronic Esters: Application to the Synthesis of Igmesine

Tim G. Elford
, Varinder K. Aggarwal^*
, Viktor Bahutski

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

72 Citations (Scopus)

Original language	English
Pages (from-to)	1080-1083
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	5
DOIs	https://doi.org/10.1002/anie.201006037
Publication status	Published - 2011

Research Groups and Themes

Organic & Biological

Keywords

azides
boronic esters
C-tertiary amines
quaternary stereocenters
trifluoroborates
ASYMMETRIC STRECKER REACTION
HIGH ENANTIOMERIC PURITIES
ENANTIOSELECTIVE SYNTHESIS
QUATERNARY STEREOCENTERS
SECONDARY-AMINES
STEREOGENIC CENTERS
MANNICH REACTIONS
CHIRAL SYNTHESIS
SIGMA-LIGAND
KETIMINES

Access to Document

10.1002/anie.201006037

Handle.net

Persistent link

NEW ASSYMETRIC REACTIONS AND THEIR APPLICATION IN TOTAL SYNTHESIS
Aggarwal, V. K. (Principal Investigator)
1/10/05 → 1/10/10
Project: Research

Cite this

@article{8a99fddccf5c4da2ba310370823486f7,

title = "Synthesis of Highly Enantioenriched C-Tertiary Amines From Boronic Esters: Application to the Synthesis of Igmesine",

keywords = "azides, boronic esters, C-tertiary amines, quaternary stereocenters, trifluoroborates, ASYMMETRIC STRECKER REACTION, HIGH ENANTIOMERIC PURITIES, ENANTIOSELECTIVE SYNTHESIS, QUATERNARY STEREOCENTERS, SECONDARY-AMINES, STEREOGENIC CENTERS, MANNICH REACTIONS, CHIRAL SYNTHESIS, SIGMA-LIGAND, KETIMINES",

author = "Elford, \{Tim G.\} and Aggarwal, \{Varinder K.\} and Viktor Bahutski",

year = "2011",

doi = "10.1002/anie.201006037",

language = "English",

volume = "50",

pages = "1080--1083",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley \& Sons, Ltd.",

number = "5",

}

TY - JOUR

T1 - Synthesis of Highly Enantioenriched C-Tertiary Amines From Boronic Esters

T2 - Application to the Synthesis of Igmesine

AU - Elford, Tim G.

AU - Aggarwal, Varinder K.

AU - Bahutski, Viktor

PY - 2011

Y1 - 2011

KW - azides

KW - boronic esters

KW - C-tertiary amines

KW - quaternary stereocenters

KW - trifluoroborates

KW - ASYMMETRIC STRECKER REACTION

KW - HIGH ENANTIOMERIC PURITIES

KW - ENANTIOSELECTIVE SYNTHESIS

KW - QUATERNARY STEREOCENTERS

KW - SECONDARY-AMINES

KW - STEREOGENIC CENTERS

KW - MANNICH REACTIONS

KW - CHIRAL SYNTHESIS

KW - SIGMA-LIGAND

KW - KETIMINES

U2 - 10.1002/anie.201006037

DO - 10.1002/anie.201006037

M3 - Article (Academic Journal)

C2 - 21268199

SN - 1433-7851

VL - 50

SP - 1080

EP - 1083

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 5

ER -

Synthesis of Highly Enantioenriched C-Tertiary Amines From Boronic Esters: Application to the Synthesis of Igmesine

Research Groups and Themes

Keywords

Access to Document

Handle.net

Projects

NEW ASSYMETRIC REACTIONS AND THEIR APPLICATION IN TOTAL SYNTHESIS

Cite this