Synthesis of Mono- and Diaza-'Pyridones' via Stille Coupling of Alkoxystannanes

Charlotte L. Smith, Christoph Hirschhaeuser, Georgia K. Malcolm, Daniel J. Nasrallah, Timothy Gallagher*

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

4 Citations (Scopus)

Abstract

Various alkoxy-substituted heterocyclic stannanes provide access to the corresponding substituted 'pyridone' moieties via Stille cross-coupling. Both pyridyl and a series of diazinyl stannanes are prepared, and options for unmasking (via demethylation or debenzylation) of the pyridone unit are evaluated.

Original languageEnglish
Pages (from-to)1904-1908
Number of pages5
JournalSYNLETT
Volume25
Issue number13
DOIs
Publication statusPublished - Aug 2014

Keywords

  • pyridine
  • heterocyclic stannane
  • Stille coupling
  • STANNYLATION REACTIONS
  • EXCHANGE-REACTIONS
  • (-)-CYTISINE
  • CYTISINE
  • ARYL

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