Synthesis of multiply ortho-substituted diaryl ethers via lithiation and oxidation of a dibenzosiloxane (phenoxasilin)

Mark S. Betson; Jonathan Clayden

doi:10.1055/s-2006-933111

Synthesis of multiply ortho-substituted diaryl ethers via lithiation and oxidation of a dibenzosiloxane (phenoxasilin)

Mark S. Betson, Jonathan Clayden^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

10 Citations (Scopus)

Abstract

Lithiation of dibenzosiloxanes (phenoxasilins or 9-silaxanthenes), followed by oxidation of the C-Si bonds, provides a versatile method for the synthesis of 2,6,2′,6′-tetrasubstituted diaryl (biaryl) ethers.

Original language	English
Pages (from-to)	745-746
Number of pages	2
Journal	Synlett
Issue number	5
Early online date	9 Mar 2006
DOIs	https://doi.org/10.1055/s-2006-933111
Publication status	Published - 17 Mar 2006

Research Groups and Themes

Organic & Biological

Keywords

Diaryl ether
ipso electrophilic aromatic substitution
Lithiation
Synthesis

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10.1055/s-2006-933111

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title = "Synthesis of multiply ortho-substituted diaryl ethers via lithiation and oxidation of a dibenzosiloxane (phenoxasilin)",

abstract = "Lithiation of dibenzosiloxanes (phenoxasilins or 9-silaxanthenes), followed by oxidation of the C-Si bonds, provides a versatile method for the synthesis of 2,6,2′,6′-tetrasubstituted diaryl (biaryl) ethers.",

keywords = "Diaryl ether, ipso electrophilic aromatic substitution, Lithiation, Synthesis",

author = "Betson, \{Mark S.\} and Jonathan Clayden",

year = "2006",

month = mar,

day = "17",

doi = "10.1055/s-2006-933111",

language = "English",

pages = "745--746",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "5",

}

TY - JOUR

T1 - Synthesis of multiply ortho-substituted diaryl ethers via lithiation and oxidation of a dibenzosiloxane (phenoxasilin)

AU - Betson, Mark S.

AU - Clayden, Jonathan

PY - 2006/3/17

Y1 - 2006/3/17

N2 - Lithiation of dibenzosiloxanes (phenoxasilins or 9-silaxanthenes), followed by oxidation of the C-Si bonds, provides a versatile method for the synthesis of 2,6,2′,6′-tetrasubstituted diaryl (biaryl) ethers.

AB - Lithiation of dibenzosiloxanes (phenoxasilins or 9-silaxanthenes), followed by oxidation of the C-Si bonds, provides a versatile method for the synthesis of 2,6,2′,6′-tetrasubstituted diaryl (biaryl) ethers.

KW - Diaryl ether

KW - ipso electrophilic aromatic substitution

KW - Lithiation

KW - Synthesis

UR - https://www.scopus.com/pages/publications/33645381709

U2 - 10.1055/s-2006-933111

DO - 10.1055/s-2006-933111

M3 - Article (Academic Journal)

AN - SCOPUS:33645381709

SN - 0936-5214

SP - 745

EP - 746

JO - Synlett

JF - Synlett

IS - 5

ER -

Synthesis of multiply ortho-substituted diaryl ethers via lithiation and oxidation of a dibenzosiloxane (phenoxasilin)

Abstract

Research Groups and Themes

Keywords

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