Synthesis of Regioselectively Functionalized Pyrenes via Transition-Metal-Catalyzed Electrocyclization

D. Barney Walker; Joshua Howgego; Anthony P. Davis

doi:10.1055/s-0030-1258238

Synthesis of Regioselectively Functionalized Pyrenes via Transition-Metal-Catalyzed Electrocyclization

D. Barney Walker, Joshua Howgego, Anthony P. Davis

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

29 Citations (Scopus)

Abstract

Transition-metal-catalyzed electrocyclic rearrangement of 2,6-diethynyl-1,1'-biphenyl precursors to form polysubstituted pyrenes is described. This method is useful for the preparation of pyrenes with uncommon substitution patterns, and selective integration of functional groups at the 1-, 2-, 3-, 5-, 7- and 9-positions is demonstrated.

Original language	English
Pages (from-to)	3686-3692
Number of pages	7
Journal	Synthesis (Germany)
Issue number	21
DOIs	https://doi.org/10.1055/s-0030-1258238
Publication status	Published - Nov 2010

Research Groups and Themes

Organic & Biological

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SYNTHETIC LECTIS FOR OLIGOSACCHARIDE BINDING IN AQUEOUS MEDIA
Davis, A. P. (Principal Investigator)
1/06/06 → 1/08/09
Project: Research

Cite this

@article{75de9445694e4bb0bdcdbd67ac89fa74,

title = "Synthesis of Regioselectively Functionalized Pyrenes via Transition-Metal-Catalyzed Electrocyclization",

abstract = "Transition-metal-catalyzed electrocyclic rearrangement of 2,6-diethynyl-1,1'-biphenyl precursors to form polysubstituted pyrenes is described. This method is useful for the preparation of pyrenes with uncommon substitution patterns, and selective integration of functional groups at the 1-, 2-, 3-, 5-, 7- and 9-positions is demonstrated.",

author = "Walker, \{D. Barney\} and Joshua Howgego and Davis, \{Anthony P.\}",

year = "2010",

month = nov,

doi = "10.1055/s-0030-1258238",

language = "English",

pages = "3686--3692",

journal = "Synthesis (Germany)",

issn = "0039-7881",

publisher = "Georg Thieme Verlag",

number = "21",

}

TY - JOUR

T1 - Synthesis of Regioselectively Functionalized Pyrenes via Transition-Metal-Catalyzed Electrocyclization

AU - Walker, D. Barney

AU - Howgego, Joshua

AU - Davis, Anthony P.

PY - 2010/11

Y1 - 2010/11

N2 - Transition-metal-catalyzed electrocyclic rearrangement of 2,6-diethynyl-1,1'-biphenyl precursors to form polysubstituted pyrenes is described. This method is useful for the preparation of pyrenes with uncommon substitution patterns, and selective integration of functional groups at the 1-, 2-, 3-, 5-, 7- and 9-positions is demonstrated.

AB - Transition-metal-catalyzed electrocyclic rearrangement of 2,6-diethynyl-1,1'-biphenyl precursors to form polysubstituted pyrenes is described. This method is useful for the preparation of pyrenes with uncommon substitution patterns, and selective integration of functional groups at the 1-, 2-, 3-, 5-, 7- and 9-positions is demonstrated.

U2 - 10.1055/s-0030-1258238

DO - 10.1055/s-0030-1258238

M3 - Article (Academic Journal)

SN - 0039-7881

SP - 3686

EP - 3692

JO - Synthesis (Germany)

JF - Synthesis (Germany)

IS - 21

ER -

Synthesis of Regioselectively Functionalized Pyrenes via Transition-Metal-Catalyzed Electrocyclization

Abstract

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SYNTHETIC LECTIS FOR OLIGOSACCHARIDE BINDING IN AQUEOUS MEDIA

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