Tandem isomerisation-carbonylation catalysis: highly active palladium(II) catalysts for the selective methoxycarbonylation of internal alkenes to linear esters

R I Pugh, E Drent, P G Pringle

Research output: Contribution to journalArticle (Academic Journal)peer-review

74 Citations (Scopus)

Abstract

Fast, selective conversion of internal olefins to linear esters is catalysed by Pd(II) complexes of chelating bis(phosphaadamantyl)diphosphines and the catalysis is acutely sensitive to the ligand backbone and even to the diastereomer used; the results are compared with those for the PBU2t analogue.

Translated title of the contributionTandem isomerisation-carbonylation catalysis: highly active palladium(II) catalysts for the selective methoxycarbonylation of internal alkenes to linear esters
Original languageEnglish
Pages (from-to)1476-1477
Number of pages2
JournalChemical Communications
Volume16
Issue number16
DOIs
Publication statusPublished - 21 Aug 2001

Bibliographical note

Publisher: Royal Society of Chemistry
Other identifier: IDS 465AD

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