Tandem isomerisation-carbonylation catalysis: highly active palladium(II) catalysts for the selective methoxycarbonylation of internal alkenes to linear esters

R I  Pugh; E  Drent; P G  Pringle

doi:10.1039/b103754b

Tandem isomerisation-carbonylation catalysis: highly active palladium(II) catalysts for the selective methoxycarbonylation of internal alkenes to linear esters

R I Pugh, E Drent, P G Pringle

School of Chemistry

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Abstract

Fast, selective conversion of internal olefins to linear esters is catalysed by Pd(II) complexes of chelating bis(phosphaadamantyl)diphosphines and the catalysis is acutely sensitive to the ligand backbone and even to the diastereomer used; the results are compared with those for the PBU2t analogue.

Translated title of the contribution	Tandem isomerisation-carbonylation catalysis: highly active palladium(II) catalysts for the selective methoxycarbonylation of internal alkenes to linear esters
Original language	English
Pages (from-to)	1476-1477
Number of pages	2
Journal	Chemical Communications
Volume	16
Issue number	16
DOIs	https://doi.org/10.1039/b103754b
Publication status	Published - 21 Aug 2001

Bibliographical note

Publisher: Royal Society of Chemistry
Other identifier: IDS 465AD

Research Groups and Themes

Inorganic & Materials

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http://www.rsc.org/Publishing/Journals/CC/article.asp?doi=b103754b

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title = "Tandem isomerisation-carbonylation catalysis: highly active palladium(II) catalysts for the selective methoxycarbonylation of internal alkenes to linear esters",

abstract = "Fast, selective conversion of internal olefins to linear esters is catalysed by Pd(II) complexes of chelating bis(phosphaadamantyl)diphosphines and the catalysis is acutely sensitive to the ligand backbone and even to the diastereomer used; the results are compared with those for the PBU2t analogue.",

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year = "2001",

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doi = "10.1039/b103754b",

language = "English",

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T1 - Tandem isomerisation-carbonylation catalysis: highly active palladium(II) catalysts for the selective methoxycarbonylation of internal alkenes to linear esters

AU - Pugh, R I

AU - Drent, E

AU - Pringle, P G

N1 - Publisher: Royal Society of Chemistry Other identifier: IDS 465AD

PY - 2001/8/21

Y1 - 2001/8/21

N2 - Fast, selective conversion of internal olefins to linear esters is catalysed by Pd(II) complexes of chelating bis(phosphaadamantyl)diphosphines and the catalysis is acutely sensitive to the ligand backbone and even to the diastereomer used; the results are compared with those for the PBU2t analogue.

AB - Fast, selective conversion of internal olefins to linear esters is catalysed by Pd(II) complexes of chelating bis(phosphaadamantyl)diphosphines and the catalysis is acutely sensitive to the ligand backbone and even to the diastereomer used; the results are compared with those for the PBU2t analogue.

U2 - 10.1039/b103754b

DO - 10.1039/b103754b

M3 - Article (Academic Journal)

SN - 1359-7345

VL - 16

SP - 1476

EP - 1477

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

Tandem isomerisation-carbonylation catalysis: highly active palladium(II) catalysts for the selective methoxycarbonylation of internal alkenes to linear esters

Abstract

Bibliographical note

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