Tellurium-doped lanthanum manganite as catalysts for the oxygen reduction reaction

V. Celorrio; L. J. Morris; M. Cattelan; N. A. Fox; D. J. Fermin

doi:10.1557/mrc.2017.22

Tellurium-doped lanthanum manganite as catalysts for the oxygen reduction reaction

V. Celorrio, L. J. Morris, M. Cattelan, N. A. Fox, D. J. Fermin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article (Academic Journal) › peer-review

8 Citations (Scopus)

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Abstract

The effect of tellurium (Te) doping on the electrocatalytic activity of La1-xTe xMnO₃ toward the oxygen reduction reaction is investigated for the first time. La1-xTe xMnO₃ with x-values up 23% were synthesized from a single ionic liquid-based precursor, yielding nanoparticles with mean diameter in the range of 40-68 nm and rhombohedral unit cell. Electrochemical studies were performed on carbon-supported particles in alkaline environment. The composition dependence activity is discussed in terms of surface density of Mn sites and changes in the effective Mn oxidation state.

Original language	English
Pages (from-to)	193-198
Number of pages	6
Journal	MRS Communications
Volume	7
Issue number	2
Early online date	9 Apr 2017
DOIs	https://doi.org/10.1557/mrc.2017.22
Publication status	Published - 1 Jun 2017

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10.1557/mrc.2017.22

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This is the author accepted manuscript (AAM). The final published version (version of record) is available online via MRS at https://www.cambridge.org/core/journals/mrs-communications/article/telluriumdoped-lanthanum-manganite-as-catalysts-for-the-oxygen-reduction-reaction/E0DA15A6CCE80025E2AA5393F0081266. Please refer to any applicable terms of use of the publisher.
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1 Finished

NanoESCA II: NanoESCA-Electron Spectroscopy for Chemical Analysis imaged at the Nanoscale (full application)
Fox, N. A.
1/05/15 → 30/04/20
Project: Research

Bristol University NanoESCA Laboratory (BrUNEL)
Neil Fox (Manager) & Mattia Cattelan (Manager)
School of Chemistry
Facility/equipment: Facility

Cite this

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title = "Tellurium-doped lanthanum manganite as catalysts for the oxygen reduction reaction",

abstract = "The effect of tellurium (Te) doping on the electrocatalytic activity of La1-xTe xMnO3 toward the oxygen reduction reaction is investigated for the first time. La1-xTe xMnO3 with x-values up 23% were synthesized from a single ionic liquid-based precursor, yielding nanoparticles with mean diameter in the range of 40-68 nm and rhombohedral unit cell. Electrochemical studies were performed on carbon-supported particles in alkaline environment. The composition dependence activity is discussed in terms of surface density of Mn sites and changes in the effective Mn oxidation state.",

author = "V. Celorrio and Morris, {L. J.} and M. Cattelan and Fox, {N. A.} and Fermin, {D. J.}",

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AU - Celorrio, V.

AU - Morris, L. J.

AU - Cattelan, M.

AU - Fox, N. A.

AU - Fermin, D. J.

PY - 2017/6/1

Y1 - 2017/6/1

N2 - The effect of tellurium (Te) doping on the electrocatalytic activity of La1-xTe xMnO3 toward the oxygen reduction reaction is investigated for the first time. La1-xTe xMnO3 with x-values up 23% were synthesized from a single ionic liquid-based precursor, yielding nanoparticles with mean diameter in the range of 40-68 nm and rhombohedral unit cell. Electrochemical studies were performed on carbon-supported particles in alkaline environment. The composition dependence activity is discussed in terms of surface density of Mn sites and changes in the effective Mn oxidation state.

AB - The effect of tellurium (Te) doping on the electrocatalytic activity of La1-xTe xMnO3 toward the oxygen reduction reaction is investigated for the first time. La1-xTe xMnO3 with x-values up 23% were synthesized from a single ionic liquid-based precursor, yielding nanoparticles with mean diameter in the range of 40-68 nm and rhombohedral unit cell. Electrochemical studies were performed on carbon-supported particles in alkaline environment. The composition dependence activity is discussed in terms of surface density of Mn sites and changes in the effective Mn oxidation state.

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U2 - 10.1557/mrc.2017.22

DO - 10.1557/mrc.2017.22

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EP - 198

JO - MRS Communications

JF - MRS Communications

SN - 2159-6859

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ER -

Tellurium-doped lanthanum manganite as catalysts for the oxygen reduction reaction

Abstract

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NanoESCA II: NanoESCA-Electron Spectroscopy for Chemical Analysis imaged at the Nanoscale (full application)

Bristol University NanoESCA Laboratory (BrUNEL)

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