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UV irradiation of various electron deficient pyrrole derivatives induces a novel methathesis sequence resulting in selective cleavage of the 2,3-pyrrole bond. The overall sequence has been shown to proceed by two discrete wavelength-dependent steps involving sequential [2+2] cyclobutane formation followed by photochemically mediated retro-[2+2] to the products. Copyright © 2007 American Chemical Society.
Bibliographical notePublisher: American Chemical Society
FingerprintDive into the research topics of 'The intramolecular photometathesis of pyrroles'. Together they form a unique fingerprint.
- 1 Finished
Booker-Milburn, K. I.
22/07/03 → 22/01/07