The intramolecular photometathesis of pyrroles

Luke D. Elliott; Malcolm Berry; Andrew J. Orr-Ewing; Kevin I. Booker-Milburn

doi:10.1021/ja070254l

The intramolecular photometathesis of pyrroles

Luke D. Elliott, Malcolm Berry, Andrew J. Orr-Ewing, Kevin I. Booker-Milburn^*

^*Corresponding author for this work

Research output: Contribution to journal › Article (Academic Journal) › peer-review

16 Citations (Scopus)

Abstract

UV irradiation of various electron deficient pyrrole derivatives induces a novel methathesis sequence resulting in selective cleavage of the 2,3-pyrrole bond. The overall sequence has been shown to proceed by two discrete wavelength-dependent steps involving sequential [2+2] cyclobutane formation followed by photochemically mediated retro-[2+2] to the products. Copyright © 2007 American Chemical Society.

Translated title of the contribution	The Intramolecular Photometathesis of Pyrroles
Original language	English
Pages (from-to)	3078-3079
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	11
DOIs	https://doi.org/10.1021/ja070254l
Publication status	Published - 21 Mar 2007

Bibliographical note

Publisher: American Chemical Society

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10.1021/ja070254l

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1 Finished

A UNIQUE HIGH POWER TUNABLE UV LASER FACILITY FOR SYNTHETIC PHOTOCHEMISTRY
Booker-Milburn, K. I.
22/07/03 → 22/01/07
Project: Research

Cite this

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title = "The intramolecular photometathesis of pyrroles",

abstract = "UV irradiation of various electron deficient pyrrole derivatives induces a novel methathesis sequence resulting in selective cleavage of the 2,3-pyrrole bond. The overall sequence has been shown to proceed by two discrete wavelength-dependent steps involving sequential [2+2] cyclobutane formation followed by photochemically mediated retro-[2+2] to the products. Copyright {\textcopyright} 2007 American Chemical Society.",

author = "Elliott, {Luke D.} and Malcolm Berry and Orr-Ewing, {Andrew J.} and Booker-Milburn, {Kevin I.}",

note = "Publisher: American Chemical Society",

year = "2007",

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day = "21",

doi = "10.1021/ja070254l",

language = "English",

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journal = "Journal of the American Chemical Society",

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AU - Elliott, Luke D.

AU - Berry, Malcolm

AU - Orr-Ewing, Andrew J.

AU - Booker-Milburn, Kevin I.

N1 - Publisher: American Chemical Society

PY - 2007/3/21

Y1 - 2007/3/21

N2 - UV irradiation of various electron deficient pyrrole derivatives induces a novel methathesis sequence resulting in selective cleavage of the 2,3-pyrrole bond. The overall sequence has been shown to proceed by two discrete wavelength-dependent steps involving sequential [2+2] cyclobutane formation followed by photochemically mediated retro-[2+2] to the products. Copyright © 2007 American Chemical Society.

AB - UV irradiation of various electron deficient pyrrole derivatives induces a novel methathesis sequence resulting in selective cleavage of the 2,3-pyrrole bond. The overall sequence has been shown to proceed by two discrete wavelength-dependent steps involving sequential [2+2] cyclobutane formation followed by photochemically mediated retro-[2+2] to the products. Copyright © 2007 American Chemical Society.

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U2 - 10.1021/ja070254l

DO - 10.1021/ja070254l

M3 - Article (Academic Journal)

C2 - 17323953

VL - 129

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EP - 3079

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 11

ER -

The intramolecular photometathesis of pyrroles

Abstract

Bibliographical note

Access to Document

A UNIQUE HIGH POWER TUNABLE UV LASER FACILITY FOR SYNTHETIC PHOTOCHEMISTRY

Cite this