The photoredox-catalyzed Meerwein addition reaction: intermolecular amino-arylation of alkenes

Durga Prasad Hari; Thea Hering; Burkhard König

doi:10.1002/anie.201307051

The photoredox-catalyzed Meerwein addition reaction: intermolecular amino-arylation of alkenes

Durga Prasad Hari, Thea Hering, Burkhard König

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

157 Citations (Scopus)

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Abstract

A variety of amides are efficiently accessible under mild conditions by intermolecular amino-arylation using a photo Meerwein addition with visible light. The reaction has a broad substrate scope, tolerates a large range of functional groups, and was applied to the synthesis of a 3-aryl-3,4-dihydroisoquinoline.

Original language	English
Pages (from-to)	725-728
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	53
Issue number	3
Early online date	4 Dec 2013
DOIs	https://doi.org/10.1002/anie.201307051
Publication status	Published - 13 Jan 2014

Bibliographical note

Acceptance date is provisional and based on date of publication.

Keywords

amino-arylation
aryl radicals
Meerwein addition
photocatalysis
visible light

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10.1002/anie.201307051

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Cite this

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AU - Hari, Durga Prasad

AU - Hering, Thea

AU - König, Burkhard

N1 - Acceptance date is provisional and based on date of publication.

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Y1 - 2014/1/13

N2 - A variety of amides are efficiently accessible under mild conditions by intermolecular amino-arylation using a photo Meerwein addition with visible light. The reaction has a broad substrate scope, tolerates a large range of functional groups, and was applied to the synthesis of a 3-aryl-3,4-dihydroisoquinoline.

AB - A variety of amides are efficiently accessible under mild conditions by intermolecular amino-arylation using a photo Meerwein addition with visible light. The reaction has a broad substrate scope, tolerates a large range of functional groups, and was applied to the synthesis of a 3-aryl-3,4-dihydroisoquinoline.

KW - amino-arylation

KW - aryl radicals

KW - Meerwein addition

KW - photocatalysis

KW - visible light

U2 - 10.1002/anie.201307051

DO - 10.1002/anie.201307051

M3 - Article (Academic Journal)

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

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ER -

The photoredox-catalyzed Meerwein addition reaction: intermolecular amino-arylation of alkenes

Abstract

Bibliographical note

Keywords

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