The Study of Reactive Intermediates in Condensed Phases

Barry Carpenter; Jeremy N Harvey; Andrew J Orr-Ewing

doi:10.1021/jacs.6b01761

The Study of Reactive Intermediates in Condensed Phases

Barry Carpenter, Jeremy N Harvey, Andrew J Orr-Ewing

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Abstract

Novel experimental techniques and computational methods have provided new insight into the behavior of reactive intermediates in solution. The results of these studies show that some of the earlier ideas about how reactive intermediates ought to behave in solution were incomplete or even incorrect. This Perspective summarizes the new experimental and computational methods and draws attention to the shortcomings that their application has brought to light in previous models. Key areas needing further research are highlighted.

Original language	English
Pages (from-to)	4695-4705
Number of pages	11
Journal	Journal of the American Chemical Society
Volume	138
Issue number	14
Early online date	23 Mar 2016
DOIs	https://doi.org/10.1021/jacs.6b01761
Publication status	Published - 13 Apr 2016

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JACS_perspective_accepted_version
Barry K. Carpenter, Jeremy N. Harvey, and Andrew J. Orr-Ewing, "The Study of Reactive Intermediates in Condensed Phases", Journal of the American Chemical Society 2016 138 (14), 4695-4705. (C) 2016 Americal Chemical Society.
Accepted author manuscript, 590 KBLicence: CC BY-NC

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abstract = "Novel experimental techniques and computational methods have provided new insight into the behavior of reactive intermediates in solution. The results of these studies show that some of the earlier ideas about how reactive intermediates ought to behave in solution were incomplete or even incorrect. This Perspective summarizes the new experimental and computational methods and draws attention to the shortcomings that their application has brought to light in previous models. Key areas needing further research are highlighted.",

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The Study of Reactive Intermediates in Condensed Phases

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