The synthesis of δ-hydroxy allylic phosphine oxides by palladium(II)-catalysed allylic transposition

Jonathan Clayden*, Eric W. Collington, Stuart Warren

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

7 Citations (Scopus)

Abstract

Palladium(II)-catalysed rearrangement of allylic acetates 5, which contain a diphenylphosphinoyl group, yields transposed acetates 6 in good yield. The reaction is mild, general for most substitution patterns, and stereospecific. The transposed acetates 6 may be hydrolysed to δ-hydroxy allylic phosphine oxides 4.

Original languageEnglish
Pages (from-to)7039-7042
Number of pages4
JournalTetrahedron Letters
Volume33
Issue number46
DOIs
Publication statusPublished - 10 Nov 1992

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