The synthesis of δ-hydroxy allylic phosphine oxides by palladium(II)-catalysed allylic transposition

Jonathan Clayden; Eric W. Collington; Stuart Warren

doi:10.1016/S0040-4039(00)60927-9

The synthesis of δ-hydroxy allylic phosphine oxides by palladium(II)-catalysed allylic transposition

Jonathan Clayden^*, Eric W. Collington, Stuart Warren

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

9 Citations (Scopus)

Abstract

Palladium(II)-catalysed rearrangement of allylic acetates 5, which contain a diphenylphosphinoyl group, yields transposed acetates 6 in good yield. The reaction is mild, general for most substitution patterns, and stereospecific. The transposed acetates 6 may be hydrolysed to δ-hydroxy allylic phosphine oxides 4.

Original language	English
Pages (from-to)	7039-7042
Number of pages	4
Journal	Tetrahedron Letters
Volume	33
Issue number	46
DOIs	https://doi.org/10.1016/S0040-4039(00)60927-9
Publication status	Published - 10 Nov 1992

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Organic & Biological

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@article{36da993823a34cbc9a819bda28be0b53,

title = "The synthesis of δ-hydroxy allylic phosphine oxides by palladium(II)-catalysed allylic transposition",

abstract = "Palladium(II)-catalysed rearrangement of allylic acetates 5, which contain a diphenylphosphinoyl group, yields transposed acetates 6 in good yield. The reaction is mild, general for most substitution patterns, and stereospecific. The transposed acetates 6 may be hydrolysed to δ-hydroxy allylic phosphine oxides 4.",

author = "Jonathan Clayden and Collington, \{Eric W.\} and Stuart Warren",

year = "1992",

month = nov,

day = "10",

doi = "10.1016/S0040-4039(00)60927-9",

language = "English",

volume = "33",

pages = "7039--7042",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "46",

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TY - JOUR

T1 - The synthesis of δ-hydroxy allylic phosphine oxides by palladium(II)-catalysed allylic transposition

AU - Clayden, Jonathan

AU - Collington, Eric W.

AU - Warren, Stuart

PY - 1992/11/10

Y1 - 1992/11/10

N2 - Palladium(II)-catalysed rearrangement of allylic acetates 5, which contain a diphenylphosphinoyl group, yields transposed acetates 6 in good yield. The reaction is mild, general for most substitution patterns, and stereospecific. The transposed acetates 6 may be hydrolysed to δ-hydroxy allylic phosphine oxides 4.

AB - Palladium(II)-catalysed rearrangement of allylic acetates 5, which contain a diphenylphosphinoyl group, yields transposed acetates 6 in good yield. The reaction is mild, general for most substitution patterns, and stereospecific. The transposed acetates 6 may be hydrolysed to δ-hydroxy allylic phosphine oxides 4.

UR - https://www.scopus.com/pages/publications/0026452042

U2 - 10.1016/S0040-4039(00)60927-9

DO - 10.1016/S0040-4039(00)60927-9

M3 - Article (Academic Journal)

AN - SCOPUS:0026452042

SN - 0040-4039

VL - 33

SP - 7039

EP - 7042

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 46

ER -

The synthesis of δ-hydroxy allylic phosphine oxides by palladium(II)-catalysed allylic transposition

Abstract

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