The voltammetric response of bipolar cells: Reversible electron transfer

Daniela Plana, Fran G.E. Jones, RAW Dryfe

Research output: Contribution to journalArticle (Academic Journal)

37 Citations (Scopus)


The voltammetric response of a bipolar cell, formed by making electrical connection between two half-cells under overall potentiostatic control, is described. Experimental data obtained with reversible redox couples are compared with numerical simulations of the corresponding two-phase transport problem, where charge transfer may be limited by the transport of either, or both, of the redox-active couples. Preliminary experiments on the extension of the system to more complex electron transfer processes, specifically metal deposition, are also described.
Original languageEnglish
JournalJournal of Electroanalytical Chemistry
Issue number1-2
Publication statusPublished - 15 Jul 2010

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