Thermal ring-opening polymerization of an unsymmetrical silicon-bridged [1]ferrocenophane in coordination nanochannels

Yuichiro Kobayashi; Kayako Honjo; Susumu Kitagawa; Jessica Gwyther; Ian Manners; Takashi Uemura

doi:10.1039/C7CC03391E

Thermal ring-opening polymerization of an unsymmetrical silicon-bridged [1]ferrocenophane in coordination nanochannels

Yuichiro Kobayashi, Kayako Honjo, Susumu Kitagawa, Jessica Gwyther, Ian Manners, Takashi Uemura

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Abstract

Thermal ring-opening polymerization of the unsymmetrically substituted [1]ferrocenophane was performed in one-dimensional nanochannels of porous coordination polymers (PCPs). In contrast to conventional thermal polymerization in bulk, formation of cyclic polymer was inhibited in the channels. In addition, the tacticity of the resulting polymer was dependent on the pore size of PCPs.

Original language	English
Pages (from-to)	6945-6948
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	51
Early online date	6 Jun 2017
DOIs	https://doi.org/10.1039/C7CC03391E
Publication status	Published - 28 Jun 2017

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This is the author accepted manuscript (AAM). The final published version (version of record) is available online via Royal Society of Chemistry at http://pubs.rsc.org/en/content/articlelanding/2017/cc/c7cc03391e#!divAbstract. Please refer to any applicable terms of use of the publisher.
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title = "Thermal ring-opening polymerization of an unsymmetrical silicon-bridged [1]ferrocenophane in coordination nanochannels",

abstract = "Thermal ring-opening polymerization of the unsymmetrically substituted [1]ferrocenophane was performed in one-dimensional nanochannels of porous coordination polymers (PCPs). In contrast to conventional thermal polymerization in bulk, formation of cyclic polymer was inhibited in the channels. In addition, the tacticity of the resulting polymer was dependent on the pore size of PCPs.",

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AU - Kobayashi, Yuichiro

AU - Honjo, Kayako

AU - Kitagawa, Susumu

AU - Gwyther, Jessica

AU - Manners, Ian

AU - Uemura, Takashi

PY - 2017/6/28

Y1 - 2017/6/28

N2 - Thermal ring-opening polymerization of the unsymmetrically substituted [1]ferrocenophane was performed in one-dimensional nanochannels of porous coordination polymers (PCPs). In contrast to conventional thermal polymerization in bulk, formation of cyclic polymer was inhibited in the channels. In addition, the tacticity of the resulting polymer was dependent on the pore size of PCPs.

AB - Thermal ring-opening polymerization of the unsymmetrically substituted [1]ferrocenophane was performed in one-dimensional nanochannels of porous coordination polymers (PCPs). In contrast to conventional thermal polymerization in bulk, formation of cyclic polymer was inhibited in the channels. In addition, the tacticity of the resulting polymer was dependent on the pore size of PCPs.

U2 - 10.1039/C7CC03391E

DO - 10.1039/C7CC03391E

M3 - Article (Academic Journal)

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JO - Chemical Communications

JF - Chemical Communications

IS - 51

ER -

Thermal ring-opening polymerization of an unsymmetrical silicon-bridged [1]ferrocenophane in coordination nanochannels

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