Transition metal free C-N bond forming dearomatizations and aryl C-H aminations by in situ release of a hydroxylamine-based aminating agent

Joshua Farndon, Xiao-Feng Ma, John Bower

Research output: Contribution to journalArticle (Academic Journal)peer-review

44 Citations (Scopus)
447 Downloads (Pure)

Abstract

We outline a simple protocol that accesses directly unprotected secondary amines by intramolecular C–N bond forming dearomatization or aryl C–H amination. The method is dependent on the generation of a potent electrophilic aminating agent released by in situ deprotection of O-Ts activated N-Boc hydroxylamines.
Original languageEnglish
Pages (from-to)14005-14008
Number of pages4
JournalJournal of the American Chemical Society
Volume139
Issue number40
Early online date27 Sep 2017
DOIs
Publication statusPublished - 11 Oct 2017

Structured keywords

  • BCS and TECS CDTs

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