Trigonal propeller-shaped [(Mn3MNa)-M-III-Na-II] complexes (M = Mn, Ca): structural and functional models for the dioxygen evolving centre of PSII

Sanjit Nayak; Hari Pada Nayek; Stefanie Dehnen; Annie K. Powell; Jan Reedijk

doi:10.1039/c0dt01463j

Trigonal propeller-shaped [(Mn3MNa)-M-III-Na-II] complexes (M = Mn, Ca): structural and functional models for the dioxygen evolving centre of PSII

Sanjit Nayak, Hari Pada Nayek, Stefanie Dehnen, Annie K. Powell, Jan Reedijk^*

^*Corresponding author for this work

School of Civil, Aerospace and Design Engineering

Research output: Contribution to journal › Article (Academic Journal) › peer-review

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Abstract

Two new polynuclear heterometallic cluster complexes with [MnIII3MIINa] (M = Mn, Ca) core were synthesized using two in situ formed Schiff bases. The compounds were structurally characterized by single crystal X-ray analysis. The compound with [MnIIICaIINa] appeared to catalyse water oxidation which was followed by using Clark electrode and online mass spectrometry.

Original language	English
Pages (from-to)	2699-2702
Number of pages	4
Journal	Dalton Transactions
Volume	40
Issue number	12
Early online date	15 Feb 2011
DOIs	https://doi.org/10.1039/c0dt01463j
Publication status	Published - 28 Mar 2011

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title = "Trigonal propeller-shaped [(Mn3MNa)-M-III-Na-II] complexes (M = Mn, Ca): structural and functional models for the dioxygen evolving centre of PSII",

abstract = "Two new polynuclear heterometallic cluster complexes with [MnIII3MIINa] (M = Mn, Ca) core were synthesized using two in situ formed Schiff bases. The compounds were structurally characterized by single crystal X-ray analysis. The compound with [MnIIICaIINa] appeared to catalyse water oxidation which was followed by using Clark electrode and online mass spectrometry.",

author = "Sanjit Nayak and Nayek, \{Hari Pada\} and Stefanie Dehnen and Powell, \{Annie K.\} and Jan Reedijk",

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T1 - Trigonal propeller-shaped [(Mn3MNa)-M-III-Na-II] complexes (M = Mn, Ca)

T2 - structural and functional models for the dioxygen evolving centre of PSII

AU - Nayak, Sanjit

AU - Nayek, Hari Pada

AU - Dehnen, Stefanie

AU - Powell, Annie K.

AU - Reedijk, Jan

PY - 2011/3/28

Y1 - 2011/3/28

N2 - Two new polynuclear heterometallic cluster complexes with [MnIII3MIINa] (M = Mn, Ca) core were synthesized using two in situ formed Schiff bases. The compounds were structurally characterized by single crystal X-ray analysis. The compound with [MnIIICaIINa] appeared to catalyse water oxidation which was followed by using Clark electrode and online mass spectrometry.

AB - Two new polynuclear heterometallic cluster complexes with [MnIII3MIINa] (M = Mn, Ca) core were synthesized using two in situ formed Schiff bases. The compounds were structurally characterized by single crystal X-ray analysis. The compound with [MnIIICaIINa] appeared to catalyse water oxidation which was followed by using Clark electrode and online mass spectrometry.

U2 - 10.1039/c0dt01463j

DO - 10.1039/c0dt01463j

M3 - Article (Academic Journal)

SN - 1477-9226

VL - 40

SP - 2699

EP - 2702

JO - Dalton Transactions

JF - Dalton Transactions

IS - 12

ER -

Trigonal propeller-shaped [(Mn3MNa)-M-III-Na-II] complexes (M = Mn, Ca): structural and functional models for the dioxygen evolving centre of PSII

Abstract

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