Tunable Surface Area, Porosity and Function in Conjugated Microporous Polymers

Jie Chen; Wei Yan; Esther Townsend; Jiangtao Feng; Long Pan; Veronica Del Angel Hernandez; Charl FJ Faul

doi:10.1002/anie.201905488

Tunable Surface Area, Porosity and Function in Conjugated Microporous Polymers

Jie Chen, Wei Yan, Esther Townsend, Jiangtao Feng, Long Pan, Veronica Del Angel Hernandez, Charl FJ Faul

Research output: Contribution to journal › Article (Academic Journal) › peer-review

52 Citations (Scopus)

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Abstract

Simple inorganic salts are used to tune N‐containing conjugated microporous polymers (CMPs) synthesized by Buchwald–Hartwig (BH) cross‐coupling reactions. Poly(triphenylamine), PTPA, initially shows a broad distribution of micropores, mesopores, and macropores. However, the addition of inorganic salts affects all porous network properties significantly: the pore size distribution is narrowed to the microporous range only, mimicking COFs and MOFs; the BET surface area is radically improved from 58 m2 g−1 to 1152 m2 g−1; and variations of the anion and cation sizes are used to fine‐tune the surface area of PTPA, with the surface area showing a gradual decrease with an increase in the ionic radius of salts. The effect of the salt on the physical properties of the polymer is attributed to adjusting and optimizing the Hansen solubility parameters (HSPs) of solvents for the growing polymer, and named the Beijing–Xi'an Jiaotong (BXJ) method.

Original language	English
Pages (from-to)	11715-11719
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	58
Issue number	34
Early online date	17 Jun 2019
DOIs	https://doi.org/10.1002/anie.201905488
Publication status	Published - 19 Aug 2019

Keywords

conjugated microporous polymer
metal-catalysed cross-couplings
tuneable properties
Hansen Solubility Parameters

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10.1002/anie.201905488

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Electroactive Porous Materials for the Selective Electrochemical Reduction of CO2
Author: Del Angel Hernandez, V., 25 Jan 2022
Supervisor: Faul, C. F. J. (Supervisor)
Student thesis: Doctoral Thesis › Doctor of Philosophy (PhD)

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Professor Charl F J Faul
- Charl.Faulbristol.acuk
- School of Chemistry - Professor of Materials Chemistry
- Cabot Institute for the Environment
- The Bristol Centre for Nanoscience and Quantum Information
- Materials for Energy
- Soft Matter, Colloids and Materials
Person: Academic , Member

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title = "Tunable Surface Area, Porosity and Function in Conjugated Microporous Polymers",

abstract = "Simple inorganic salts are used to tune N‐containing conjugated microporous polymers (CMPs) synthesized by Buchwald–Hartwig (BH) cross‐coupling reactions. Poly(triphenylamine), PTPA, initially shows a broad distribution of micropores, mesopores, and macropores. However, the addition of inorganic salts affects all porous network properties significantly: the pore size distribution is narrowed to the microporous range only, mimicking COFs and MOFs; the BET surface area is radically improved from 58 m2 g−1 to 1152 m2 g−1; and variations of the anion and cation sizes are used to fine‐tune the surface area of PTPA, with the surface area showing a gradual decrease with an increase in the ionic radius of salts. The effect of the salt on the physical properties of the polymer is attributed to adjusting and optimizing the Hansen solubility parameters (HSPs) of solvents for the growing polymer, and named the Beijing–Xi'an Jiaotong (BXJ) method.",

keywords = "conjugated microporous polymer, metal-catalysed cross-couplings, tuneable properties, Hansen Solubility Parameters",

author = "Jie Chen and Wei Yan and Esther Townsend and Jiangtao Feng and Long Pan and {Del Angel Hernandez}, Veronica and Faul, {Charl FJ}",

year = "2019",

month = aug,

day = "19",

doi = "10.1002/anie.201905488",

language = "English",

volume = "58",

pages = "11715--11719",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "Wiley-VCH Verlag",

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Tunable Surface Area, Porosity and Function in Conjugated Microporous Polymers. / Chen, Jie; Yan, Wei; Townsend, Esther; Feng, Jiangtao; Pan, Long; Del Angel Hernandez, Veronica; Faul, Charl FJ.

In: Angewandte Chemie - International Edition, Vol. 58, No. 34, 19.08.2019, p. 11715-11719.

Research output: Contribution to journal › Article (Academic Journal) › peer-review

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T1 - Tunable Surface Area, Porosity and Function in Conjugated Microporous Polymers

AU - Chen, Jie

AU - Yan, Wei

AU - Townsend, Esther

AU - Feng, Jiangtao

AU - Pan, Long

AU - Del Angel Hernandez, Veronica

AU - Faul, Charl FJ

PY - 2019/8/19

Y1 - 2019/8/19

N2 - Simple inorganic salts are used to tune N‐containing conjugated microporous polymers (CMPs) synthesized by Buchwald–Hartwig (BH) cross‐coupling reactions. Poly(triphenylamine), PTPA, initially shows a broad distribution of micropores, mesopores, and macropores. However, the addition of inorganic salts affects all porous network properties significantly: the pore size distribution is narrowed to the microporous range only, mimicking COFs and MOFs; the BET surface area is radically improved from 58 m2 g−1 to 1152 m2 g−1; and variations of the anion and cation sizes are used to fine‐tune the surface area of PTPA, with the surface area showing a gradual decrease with an increase in the ionic radius of salts. The effect of the salt on the physical properties of the polymer is attributed to adjusting and optimizing the Hansen solubility parameters (HSPs) of solvents for the growing polymer, and named the Beijing–Xi'an Jiaotong (BXJ) method.

AB - Simple inorganic salts are used to tune N‐containing conjugated microporous polymers (CMPs) synthesized by Buchwald–Hartwig (BH) cross‐coupling reactions. Poly(triphenylamine), PTPA, initially shows a broad distribution of micropores, mesopores, and macropores. However, the addition of inorganic salts affects all porous network properties significantly: the pore size distribution is narrowed to the microporous range only, mimicking COFs and MOFs; the BET surface area is radically improved from 58 m2 g−1 to 1152 m2 g−1; and variations of the anion and cation sizes are used to fine‐tune the surface area of PTPA, with the surface area showing a gradual decrease with an increase in the ionic radius of salts. The effect of the salt on the physical properties of the polymer is attributed to adjusting and optimizing the Hansen solubility parameters (HSPs) of solvents for the growing polymer, and named the Beijing–Xi'an Jiaotong (BXJ) method.

KW - conjugated microporous polymer

KW - metal-catalysed cross-couplings

KW - tuneable properties

KW - Hansen Solubility Parameters

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DO - 10.1002/anie.201905488

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

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ER -

Tunable Surface Area, Porosity and Function in Conjugated Microporous Polymers

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Student Theses

Electroactive Porous Materials for the Selective Electrochemical Reduction of CO2

Profiles

Professor Charl F J Faul

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