Two edge-sharing MnII4MnIII6 supertetrahedra
give an anisotropic S = 28 ± 1 MnII6MnIII11 complex

Sanjit  Nayak; Lianne M. C. Beltran; Yanhua Lan; Rodolphe Clerac; Nigel G. R. Hearns; Wolfgang Wernsdorfer; Christopher E.  Anson; Annie K. Powell

doi:10.1039/b820818m

Two edge-sharing Mn^II₄Mn^III₆ supertetrahedra give an anisotropic S = 28 ± 1 Mn^II₆Mn^III₁₁ complex

Sanjit Nayak, Lianne M. C. Beltran, Yanhua Lan, Rodolphe Clerac, Nigel G. R. Hearns, Wolfgang Wernsdorfer, Christopher E. Anson, Annie K. Powell^*

^*Corresponding author for this work

School of Civil, Aerospace and Design Engineering

Research output: Contribution to journal › Article (Academic Journal) › peer-review

35 Citations (Scopus)

Abstract

A complex with a [Mn^II₆Mn^III₁₁] core results via formal fusion of two isotropic Mn^II₄Mn^III₆ supertetrahedra along a common edge leading to a high spin ground state anisotropic system showing Mvs. H hysteresis loops below 1 K.

Original language	English
Pages (from-to)	1901-1903
Number of pages	3
Journal	Dalton Transactions
Volume	2009
Issue number	11
Early online date	10 Feb 2009
DOIs	https://doi.org/10.1039/b820818m
Publication status	Published - 21 Mar 2009

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@article{9f5b6f7e080b42e5995823e31ee3d35a,

title = "Two edge-sharing MnII4MnIII6 supertetrahedra give an anisotropic S = 28 ± 1 MnII6MnIII11 complex ",

abstract = "A complex with a [MnII6MnIII11] core results via formal fusion of two isotropic MnII4MnIII6 supertetrahedra along a common edge leading to a high spin ground state anisotropic system showing Mvs. H hysteresis loops below 1 K.",

author = "Sanjit Nayak and Beltran, {Lianne M. C.} and Yanhua Lan and Rodolphe Clerac and Hearns, {Nigel G. R.} and Wolfgang Wernsdorfer and Anson, {Christopher E.} and Powell, {Annie K.}",

year = "2009",

month = mar,

day = "21",

doi = "10.1039/b820818m",

language = "English",

volume = "2009",

pages = "1901--1903",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "11",

}

TY - JOUR

T1 - Two edge-sharing MnII4MnIII6 supertetrahedra give an anisotropic S = 28 ± 1 MnII6MnIII11 complex

AU - Nayak, Sanjit

AU - Beltran, Lianne M. C.

AU - Lan, Yanhua

AU - Clerac, Rodolphe

AU - Hearns, Nigel G. R.

AU - Wernsdorfer, Wolfgang

AU - Anson, Christopher E.

AU - Powell, Annie K.

PY - 2009/3/21

Y1 - 2009/3/21

N2 - A complex with a [MnII6MnIII11] core results via formal fusion of two isotropic MnII4MnIII6 supertetrahedra along a common edge leading to a high spin ground state anisotropic system showing Mvs. H hysteresis loops below 1 K.

AB - A complex with a [MnII6MnIII11] core results via formal fusion of two isotropic MnII4MnIII6 supertetrahedra along a common edge leading to a high spin ground state anisotropic system showing Mvs. H hysteresis loops below 1 K.

U2 - 10.1039/b820818m

DO - 10.1039/b820818m

M3 - Article (Academic Journal)

SN - 1477-9226

VL - 2009

SP - 1901

EP - 1903

JO - Dalton Transactions

JF - Dalton Transactions

IS - 11

ER -

Two edge-sharing MnII4MnIII6 supertetrahedra give an anisotropic S = 28 ± 1 MnII6MnIII11 complex

Abstract

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Two edge-sharing Mn^II₄Mn^III₆ supertetrahedra give an anisotropic S = 28 ± 1 Mn^II₆Mn^III₁₁ complex