Understanding irradiation-induced nanoprecipitation in zirconium alloys using parallel TEM and APT

A. Harte*, R. Prasath Babu, C. A. Hirst, Tomas L Martin, P. A.J. Bagot, M. P. Moody, P. Frankel, J. Romero, L. Hallstadius, E. C. Darby, M. Preuss

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

17 Citations (Scopus)
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We investigate nano-scale irradiation-induced precipitation in a Zr–Sn–Fe–Cr–Ni-alloy (Zircaloy-2) by combining atom probe tomography (APT) for chemical detail with scanning transmission electron microscopy (STEM) and high resolution energy dispersive X-ray (EDX) spectroscopy for wider context and complimentary and correlative TEM diffraction techniques for crystallographic relationships. We find that Fe– and Cr-rich nano-rods precipitate in Zircaloy-2 following proton irradiation at 350 °C to a low dose of ∼2 dpa. The long-axis of the nano-rods are aligned in a direction 12–15° from the Zr matrix 〈0001〉 align in the basal plane and are of width 1.5–5 nm. Smaller rods are of APT-determined composition Zr4(Fe0.67Cr0.33), tending towards Zr3(Fe0.69Cr0.31) as the rod volume increases to > ∼400 nm3, in agreement with STEM-EDX determination of composition resembling that of Zr3Fe with Cr replacing some of the Fe. The Fe/Cr ratio has been shown to increase with distance from the nearest partially-dissolved Zr(Fe,Cr)2 phase particle. The nucleation of nano rods has implications for macroscopic irradiation-induced deformation phenomena, irradiation-induced hardening and the evolution of dislocation loops and other defects.

Original languageEnglish
Pages (from-to)460-471
Number of pages12
JournalJournal of Nuclear Materials
Early online date17 Aug 2018
Publication statusPublished - 1 Nov 2018


  • Atom probe tomography
  • Irradiation
  • Nano precipitation
  • Transmission electron microscopy
  • Zirconium


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