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Using chirality to influence supramolecular gelation

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Using chirality to influence supramolecular gelation. / McAulay, Kate; Dietrich, Bart; Su, Hao; Scott, Michael T.; Rogers, Sarah; Al-Hilaly, Youssra K.; Cui, Honggang; Serpell, Louise C.; Seddon, Annela M.; Draper, Emily R.; Adams, Dave J.

In: Chemical Science, Vol. 10, No. 33, 03.07.2019, p. 7801-7806.

Research output: Contribution to journalArticle

Harvard

McAulay, K, Dietrich, B, Su, H, Scott, MT, Rogers, S, Al-Hilaly, YK, Cui, H, Serpell, LC, Seddon, AM, Draper, ER & Adams, DJ 2019, 'Using chirality to influence supramolecular gelation', Chemical Science, vol. 10, no. 33, pp. 7801-7806. https://doi.org/10.1039/c9sc02239b

APA

McAulay, K., Dietrich, B., Su, H., Scott, M. T., Rogers, S., Al-Hilaly, Y. K., ... Adams, D. J. (2019). Using chirality to influence supramolecular gelation. Chemical Science, 10(33), 7801-7806. https://doi.org/10.1039/c9sc02239b

Vancouver

McAulay K, Dietrich B, Su H, Scott MT, Rogers S, Al-Hilaly YK et al. Using chirality to influence supramolecular gelation. Chemical Science. 2019 Jul 3;10(33):7801-7806. https://doi.org/10.1039/c9sc02239b

Author

McAulay, Kate ; Dietrich, Bart ; Su, Hao ; Scott, Michael T. ; Rogers, Sarah ; Al-Hilaly, Youssra K. ; Cui, Honggang ; Serpell, Louise C. ; Seddon, Annela M. ; Draper, Emily R. ; Adams, Dave J. / Using chirality to influence supramolecular gelation. In: Chemical Science. 2019 ; Vol. 10, No. 33. pp. 7801-7806.

Bibtex

@article{8a34d56fa92b4f4c8e1acb5ca4b64a05,
title = "Using chirality to influence supramolecular gelation",
abstract = "Most low molecular weight gelators are chiral, with racemic mixtures often unable to form gels. Here, we show an example where all enantiomers, diastereomers and racemates of a single functionalized dipeptide can form gels. At high pH, different self-assembled aggregates are formed and these directly template the structures formed in the gel. Hence, solutions and gels with different properties can be accessed simply by varying the chirality. This opens up new design rules for the field.",
author = "Kate McAulay and Bart Dietrich and Hao Su and Scott, {Michael T.} and Sarah Rogers and Al-Hilaly, {Youssra K.} and Honggang Cui and Serpell, {Louise C.} and Seddon, {Annela M.} and Draper, {Emily R.} and Adams, {Dave J.}",
year = "2019",
month = "7",
day = "3",
doi = "10.1039/c9sc02239b",
language = "English",
volume = "10",
pages = "7801--7806",
journal = "Chemical Science",
issn = "2041-6520",
publisher = "Royal Society of Chemistry",
number = "33",

}

RIS - suitable for import to EndNote

TY - JOUR

T1 - Using chirality to influence supramolecular gelation

AU - McAulay, Kate

AU - Dietrich, Bart

AU - Su, Hao

AU - Scott, Michael T.

AU - Rogers, Sarah

AU - Al-Hilaly, Youssra K.

AU - Cui, Honggang

AU - Serpell, Louise C.

AU - Seddon, Annela M.

AU - Draper, Emily R.

AU - Adams, Dave J.

PY - 2019/7/3

Y1 - 2019/7/3

N2 - Most low molecular weight gelators are chiral, with racemic mixtures often unable to form gels. Here, we show an example where all enantiomers, diastereomers and racemates of a single functionalized dipeptide can form gels. At high pH, different self-assembled aggregates are formed and these directly template the structures formed in the gel. Hence, solutions and gels with different properties can be accessed simply by varying the chirality. This opens up new design rules for the field.

AB - Most low molecular weight gelators are chiral, with racemic mixtures often unable to form gels. Here, we show an example where all enantiomers, diastereomers and racemates of a single functionalized dipeptide can form gels. At high pH, different self-assembled aggregates are formed and these directly template the structures formed in the gel. Hence, solutions and gels with different properties can be accessed simply by varying the chirality. This opens up new design rules for the field.

UR - http://www.scopus.com/inward/record.url?scp=85071226827&partnerID=8YFLogxK

U2 - 10.1039/c9sc02239b

DO - 10.1039/c9sc02239b

M3 - Article

VL - 10

SP - 7801

EP - 7806

JO - Chemical Science

JF - Chemical Science

SN - 2041-6520

IS - 33

ER -