Versatile and controlled functionalization of polyferrocenylsilane-b-polyvinylsiloxane block copolymers using a N-hydroxysuccinimidyl ester strategy

Charlotte Boott, David Lunn, Ian Manners

Research output: Contribution to journalArticle (Academic Journal)peer-review

5 Citations (Scopus)
215 Downloads (Pure)

Abstract

A general route for the N-hydroxysuccinimidyl ester functionalisation of poly(ferrocenyldimethyl)silane-b-polyvinylsiloxane copolymers, which should be readily transferrable to other vinyl containing polymers, has been developed using a simple two step approach. Facile reaction of the N-hydroxysuccinimidyl (NHS) ester functionalised polymers with primary amines enables the incorporation of a range of functionalities previously inaccessible using standard thiol-ene “click” reactions.
Original languageEnglish
Pages (from-to)245-252
Number of pages8
JournalJournal of Polymer Science Part A: Polymer Chemistry
Volume54
Issue number2
Early online date14 Jul 2015
DOIs
Publication statusPublished - 8 Dec 2015

Structured keywords

  • BCS and TECS CDTs

Keywords

  • block copolymers
  • functionalization of polymers
  • inorganic polymers
  • polysiloxanes
  • synthesis

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