Versatile and controlled functionalization of polyferrocenylsilane-b-polyvinylsiloxane block copolymers using a N-hydroxysuccinimidyl ester strategy

Charlotte Boott; David Lunn; Ian Manners

doi:10.1002/pola.27727

Versatile and controlled functionalization of polyferrocenylsilane-b-polyvinylsiloxane block copolymers using a N-hydroxysuccinimidyl ester strategy

Charlotte Boott, David Lunn, Ian Manners

Research output: Contribution to journal › Article (Academic Journal) › peer-review

10 Citations (Scopus)

334 Downloads (Pure)

Abstract

A general route for the N-hydroxysuccinimidyl ester functionalisation of poly(ferrocenyldimethyl)silane-b-polyvinylsiloxane copolymers, which should be readily transferrable to other vinyl containing polymers, has been developed using a simple two step approach. Facile reaction of the N-hydroxysuccinimidyl (NHS) ester functionalised polymers with primary amines enables the incorporation of a range of functionalities previously inaccessible using standard thiol-ene “click” reactions.

Original language	English
Pages (from-to)	245-252
Number of pages	8
Journal	Journal of Polymer Science Part A: Polymer Chemistry
Volume	54
Issue number	2
Early online date	14 Jul 2015
DOIs	https://doi.org/10.1002/pola.27727
Publication status	Published - 8 Dec 2015

Research Groups and Themes

BCS and TECS CDTs

Keywords

block copolymers
functionalization of polymers
inorganic polymers
polysiloxanes
synthesis

Access to Document

10.1002/pola.27727

CEB_NHS_Ester_Functionalisation_V2.0
This is the author accepted manuscript (AAM). The final published version (version of record) is available online via Wiley at http://dx.doi.org/10.1002/pola.27727. Please refer to any applicable terms of use of the publisher.
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3-month Core Capability for Chemistry Research
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Cite this

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title = "Versatile and controlled functionalization of polyferrocenylsilane-b-polyvinylsiloxane block copolymers using a N-hydroxysuccinimidyl ester strategy",

abstract = "A general route for the N-hydroxysuccinimidyl ester functionalisation of poly(ferrocenyldimethyl)silane-b-polyvinylsiloxane copolymers, which should be readily transferrable to other vinyl containing polymers, has been developed using a simple two step approach. Facile reaction of the N-hydroxysuccinimidyl (NHS) ester functionalised polymers with primary amines enables the incorporation of a range of functionalities previously inaccessible using standard thiol-ene “click” reactions.",

keywords = "block copolymers, functionalization of polymers, inorganic polymers, polysiloxanes, synthesis",

author = "Charlotte Boott and David Lunn and Ian Manners",

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journal = "Journal of Polymer Science Part A: Polymer Chemistry",

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Versatile and controlled functionalization of polyferrocenylsilane-b-polyvinylsiloxane block copolymers using a N-hydroxysuccinimidyl ester strategy. / Boott, Charlotte; Lunn, David; Manners, Ian.
In: Journal of Polymer Science Part A: Polymer Chemistry, Vol. 54, No. 2, 08.12.2015, p. 245-252.

Research output: Contribution to journal › Article (Academic Journal) › peer-review

TY - JOUR

T1 - Versatile and controlled functionalization of polyferrocenylsilane-b-polyvinylsiloxane block copolymers using a N-hydroxysuccinimidyl ester strategy

AU - Boott, Charlotte

AU - Lunn, David

AU - Manners, Ian

PY - 2015/12/8

Y1 - 2015/12/8

N2 - A general route for the N-hydroxysuccinimidyl ester functionalisation of poly(ferrocenyldimethyl)silane-b-polyvinylsiloxane copolymers, which should be readily transferrable to other vinyl containing polymers, has been developed using a simple two step approach. Facile reaction of the N-hydroxysuccinimidyl (NHS) ester functionalised polymers with primary amines enables the incorporation of a range of functionalities previously inaccessible using standard thiol-ene “click” reactions.

AB - A general route for the N-hydroxysuccinimidyl ester functionalisation of poly(ferrocenyldimethyl)silane-b-polyvinylsiloxane copolymers, which should be readily transferrable to other vinyl containing polymers, has been developed using a simple two step approach. Facile reaction of the N-hydroxysuccinimidyl (NHS) ester functionalised polymers with primary amines enables the incorporation of a range of functionalities previously inaccessible using standard thiol-ene “click” reactions.

KW - block copolymers

KW - functionalization of polymers

KW - inorganic polymers

KW - polysiloxanes

KW - synthesis

U2 - 10.1002/pola.27727

DO - 10.1002/pola.27727

M3 - Article (Academic Journal)

SN - 0887-624X

VL - 54

SP - 245

EP - 252

JO - Journal of Polymer Science Part A: Polymer Chemistry

JF - Journal of Polymer Science Part A: Polymer Chemistry

IS - 2

ER -

Versatile and controlled functionalization of polyferrocenylsilane-b-polyvinylsiloxane block copolymers using a N-hydroxysuccinimidyl ester strategy

Abstract

Research Groups and Themes

Keywords

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