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Carbonylative C-C Bond Activation of Electron-Poor Cyclopropanes: Rhodium‐Catalyzed (3+1+2) Cycloadditions of Cyclopropylamides

Research output: Contribution to journalArticle

Original languageEnglish
Pages (from-to)221-225
Number of pages5
JournalAngewandte Chemie - International Edition
Volume58
Issue number1
Early online date29 Nov 2018
DOIs
DateAccepted/In press - 5 Nov 2018
DateE-pub ahead of print - 29 Nov 2018
DatePublished (current) - 2 Jan 2019

Abstract

Rh‐catalyzed carbonylative C−C bond activation of cyclopropylamides generates configurationally stable rhodacyclopentanones that engage tethered alkenes in (3+1+2) cycloadditions. These studies provide the first examples of multicomponent cycloadditions that proceed through C−C bond activation of “simple” electron poor cyclopropanes.

    Research areas

  • C−C activation, cycloaddition, cyclopropane, rhodium

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  • Full-text PDF (accepted author manuscript)

    Rights statement: This is the author accepted manuscript (AAM). The final published version (version of record) is available online via Wiley-VCH at https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201811460 . Please refer to any applicable terms of use of the publisher.

    Accepted author manuscript, 1 MB, PDF document

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